{"id":"W4400111866","doi":"10.1021/acscatal.4c00675","title":"Uncovering Electrochemical Methane Oxidation Mechanism through the In Situ Detection of Reaction Intermediates","year":2024,"lang":"en","type":"article","venue":"ACS Catalysis","topic":"Electrocatalysts for Energy Conversion","field":"Energy","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta; University of Calgary","funders":"Alberta Innovates; Canada First Research Excellence Fund; Government of Alberta","keywords":"Formate; Chemistry; Formic acid; Catalysis; Electrochemistry; Reaction intermediate; Photochemistry; Redox; Reaction mechanism; Inorganic chemistry; Faraday efficiency; Methane; Adsorption; Electrode; Organic chemistry; Physical chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002312225,0.0004067053,0.0001924648,0.0002218589,0.0001265738,0.0002844583,0.0004819641,0.0006543489,0.0007498414],"category_scores_gemma":[0.0002949124,0.0001933558,0.0001795001,0.0001284576,0.0003206548,0.0004502634,0.0002107552,0.0005510075,0.0001693069],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002503624,"about_ca_system_score_gemma":0.00012523,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004123446,"about_ca_topic_score_gemma":0.0008186026,"domain_scores_codex":[0.9998729,0.00001766079,0.000006822868,0.00003024335,0.00003983109,0.00003251136],"domain_scores_gemma":[0.9999322,0.00002594525,0.00001925396,0.000006806881,0.00001026301,0.000005455854],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002969489,0.00001608419,0.0002114288,0.00005092529,0.000004019337,0.00004515674,0.00001609593,0.00008815556,0.9977759,0.0001950666,0.00002955081,0.001537939],"study_design_scores_gemma":[0.000002718281,0.00004896848,0.0004310936,0.00000260097,0.00000596507,0.00004906749,0.00002042243,0.001777256,0.9970165,0.00008855081,0.0005538362,0.000003011193],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9542749,0.002480488,0.03861333,0.0004257685,0.000105279,0.00006823953,0.0003761014,0.0002824081,0.003373521],"genre_scores_gemma":[0.9871656,0.0009498381,0.01073975,0.00005139754,0.00001342936,0.00002005412,0.0001125009,0.000006647628,0.0009408012],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007498414,"threshold_uncertainty_score":0.002508521,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006553755531970872,"score_gpt":0.2263070666041049,"score_spread":0.219753311072134,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}