{"id":"W4400317517","doi":"10.1002/anie.202411635","title":"Formation of a Decanuclear Organometallic Dysprosium Complex via a Radical–Radical Cross–Coupling Reaction","year":2024,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Magnetism in coordination complexes","field":"Materials Science","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; Office of Science; U.S. Department of Energy; Stavros Niarchos Foundation; Basic Energy Sciences; University of South Dakota; Canada Foundation for Innovation; National Science Foundation","keywords":"Chemistry; Pyrazine; Reactivity (psychology); Dysprosium; Ligand (biochemistry); Coupling reaction; Metal; Photochemistry; Group 2 organometallic chemistry; Computational chemistry; Crystallography; Stereochemistry; Inorganic chemistry; Molecule; Organic chemistry; Catalysis; Receptor","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004537965,0.0001701615,0.0001885849,0.0002643492,0.0001191521,0.0002518738,0.0003183161,0.0001203836,0.005166461],"category_scores_gemma":[0.0001882649,0.000171939,0.0001096979,0.0002895726,0.0002466019,0.001213069,0.00009246187,0.0001676204,0.0002790762],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002780059,"about_ca_system_score_gemma":0.00005777786,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007060616,"about_ca_topic_score_gemma":0.00001044591,"domain_scores_codex":[0.9981173,0.00002262866,0.0005619776,0.0003643069,0.0007265951,0.000207137],"domain_scores_gemma":[0.9990548,0.0001692295,0.0001993173,0.0001805228,0.0003124261,0.00008370729],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004636227,0.00006992472,0.00002319853,0.0001246341,0.00001577003,0.000006161461,0.00017369,0.00008751441,0.9898196,0.002225272,0.006434288,0.0009735383],"study_design_scores_gemma":[0.0003279186,0.00005881986,0.0008767403,0.0001176278,0.00002400361,0.00006967395,0.00002878512,0.0236957,0.9349995,0.002578233,0.03705497,0.0001679923],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7632638,0.000278107,0.2161075,0.003852401,0.006426297,0.0004565582,0.0003418778,0.00063099,0.008642454],"genre_scores_gemma":[0.9955631,0.0000425435,0.00196097,0.000118393,0.001288393,0.00005100792,0.0006354952,0.00002919559,0.0003108754],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2322993,"threshold_uncertainty_score":0.995743,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02573022008914709,"score_gpt":0.2919190974550551,"score_spread":0.266188877365908,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}