{"id":"W4400317698","doi":"10.1002/ange.202411635","title":"Formation of a Decanuclear Organometallic Dysprosium Complex via a Radical–Radical Cross–Coupling Reaction","year":2024,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; Office of Science; U.S. Department of Energy; Stavros Niarchos Foundation; Basic Energy Sciences; University of South Dakota; Canada Foundation for Innovation; National Science Foundation","keywords":"Chemistry; Dysprosium; Coupling reaction; Organometallic chemistry; Photochemistry; Computational chemistry; Organic chemistry; Inorganic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001282657,0.0002051438,0.0001879076,0.0001205496,0.0001559711,0.00023935,0.0004437702,0.0002812208,0.001547059],"category_scores_gemma":[0.0001773241,0.0001266645,0.000141174,0.00009385798,0.0001584686,0.0001894147,0.0003600416,0.0003258661,0.0003099514],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003771087,"about_ca_system_score_gemma":0.00023893,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005600455,"about_ca_topic_score_gemma":0.0009696498,"domain_scores_codex":[0.9999005,0.00001090186,0.000007624703,0.00002848368,0.0000224278,0.00003010118],"domain_scores_gemma":[0.9999548,0.000006002984,0.00001042246,0.000009952107,0.000006940431,0.00001197379],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001193411,0.00007189041,0.0001968686,0.0003032443,0.00003463596,0.0003922002,0.0001501024,0.0007332783,0.9860238,0.004297182,0.000687297,0.006990174],"study_design_scores_gemma":[0.00006255311,0.0003248286,0.000531866,0.000007597888,0.0000199425,0.0003425991,0.00002679959,0.003109637,0.9874164,0.0002413003,0.00789849,0.00001806174],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9836845,0.0008208874,0.007477384,0.0002173356,0.00009922896,0.0001127566,0.000144729,0.0001618444,0.007281414],"genre_scores_gemma":[0.9941924,0.0002142464,0.003330211,0.00003579355,0.000003906075,0.00002018008,0.00005880953,0.00001226131,0.002132282],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001547059,"threshold_uncertainty_score":0.005175471,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02410973535386007,"score_gpt":0.2589025141808213,"score_spread":0.2347927788269613,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}