{"id":"W4400330331","doi":"10.1039/d4dt01488j","title":"Emissive supramolecular ionic crystals combining a red-NIR phosphorescent [Re<sub>6</sub>Se<sub>8</sub>CN<sub>6</sub>]<sup>4−</sup> cluster anion and a blue fluorescent tetraphenylethene counter-cation","year":2024,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Inorganic Chemistry and Materials","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Institute of Circulatory and Respiratory Health; Ambassade de France à Moscou; Russian Science Foundation","keywords":"Phosphorescence; Tetraphenylethylene; Dication; Fluorescence; Supramolecular chemistry; Ion; Photochemistry; Cluster (spacecraft); Ionic bonding; Octahedron; Chemistry; Materials science; Crystallography; Crystal structure; Aggregation-induced emission; Organic chemistry; Optics","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008412341,0.0002048934,0.0001662552,0.0001167139,0.0001512433,0.0004520717,0.0003579284,0.0002360221,0.002793056],"category_scores_gemma":[0.0001506241,0.0001211079,0.000101903,0.0001337668,0.000217043,0.0002903255,0.0003610745,0.0003393532,0.0007446092],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002507365,"about_ca_system_score_gemma":0.0001697999,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000193842,"about_ca_topic_score_gemma":0.0005644765,"domain_scores_codex":[0.9999006,0.00001226742,0.000005780815,0.00002835943,0.00003093107,0.00002216007],"domain_scores_gemma":[0.9999139,0.00001168239,0.00002861912,0.00000968859,0.00001395756,0.000022178],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007120481,0.0000209745,0.0001321608,0.00004274092,0.000007417518,0.00003523802,0.00001133758,0.0001227244,0.9968279,0.0006917851,0.000213791,0.001822795],"study_design_scores_gemma":[0.00001737861,0.00009365011,0.0006912126,0.000003619253,0.00001293981,0.000172288,0.00002028443,0.0008715849,0.9941367,0.0001133181,0.003860047,0.000006914488],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9774596,0.0004706904,0.008123475,0.0001240981,0.00008405487,0.00003403737,0.0004019286,0.0005110333,0.01279123],"genre_scores_gemma":[0.9856452,0.0001270599,0.005912805,0.0000788996,0.00001472286,0.00002706032,0.0003235426,0.00006189274,0.007808822],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002793056,"threshold_uncertainty_score":0.009343684,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008488795521706791,"score_gpt":0.223723119947018,"score_spread":0.2152343244253112,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}