{"id":"W4400344032","doi":"10.1021/acscatal.4c02369","title":"Surface-Bound Formate Oxyanions Destabilize Hydration Layers to Pave OH<sup>–</sup> Transport Pathways for Oxygen Evolution","year":2024,"lang":"en","type":"article","venue":"ACS Catalysis","topic":"Electrocatalysts for Energy Conversion","field":"Energy","cited_by":32,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Program of Shanghai Academic Research Leader; Science and Technology Commission of Shanghai Municipality; National Natural Science Foundation of China","keywords":"Formate; Catalysis; Chemistry; Oxygen; Oxygen evolution; Oxygen transport; Inorganic chemistry; Electrochemistry; Physical chemistry; Organic chemistry; Electrode","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0006147728,0.0004222917,0.0004293032,0.0004221557,0.0004007501,0.0001314691,0.0004025023,0.0002641417,0.00009364033],"category_scores_gemma":[0.0000978723,0.0004221417,0.0004524471,0.001469835,0.00006007001,0.0009979215,0.0000616359,0.000198479,0.0004723254],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001088295,"about_ca_system_score_gemma":0.0002572948,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002437406,"about_ca_topic_score_gemma":0.002879076,"domain_scores_codex":[0.9971598,0.00006068419,0.0006240745,0.0008084525,0.0005891129,0.0007578966],"domain_scores_gemma":[0.9984414,0.0001856431,0.0000914902,0.0007556826,0.0002624065,0.0002634037],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002787789,0.0001745561,0.0003004462,0.0003488107,0.001019662,0.00003480594,0.006959904,0.3844451,0.5372262,0.0595657,0.002468986,0.007177068],"study_design_scores_gemma":[0.002048454,0.0007681295,0.0007210979,0.0002456481,0.002618165,0.00007591853,0.002865345,0.1717797,0.6788803,0.01309708,0.1245431,0.002357151],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9745906,0.0004009567,0.02103672,0.0006891635,0.0002295105,0.0005655979,0.00008262002,0.0006732749,0.001731555],"genre_scores_gemma":[0.9938471,0.00005335498,0.0009170547,0.0001278936,0.0001678335,0.0002057156,0.003249462,0.000121864,0.001309737],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2126654,"threshold_uncertainty_score":0.999823,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01331407880366893,"score_gpt":0.2265543343530867,"score_spread":0.2132402555494178,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}