{"id":"W4400349334","doi":"10.1021/jacs.4c03685","title":"Enantioselective Carbon Isotope Exchange","year":2024,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Chemical Reactions and Isotopes","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada; Mitacs; Killam Trusts; Canada Foundation for Innovation","keywords":"Chemistry; Enantioselective synthesis; Isotopes of carbon; Carbon fibers; Organic chemistry; Catalysis; Total organic carbon","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003762713,0.0001360971,0.0002700078,0.00002148176,0.00008030589,0.00002719093,0.0003291412,0.0001090326,0.0001792566],"category_scores_gemma":[0.0001246082,0.00008205249,0.0006050097,0.0005255776,0.0004353354,0.00006883515,0.0001013529,0.001399029,0.000009686048],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002408046,"about_ca_system_score_gemma":0.0001164297,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000345094,"about_ca_topic_score_gemma":6.658242e-7,"domain_scores_codex":[0.9990054,0.00009445847,0.0002968602,0.000143336,0.0002011283,0.0002588256],"domain_scores_gemma":[0.9990029,0.0004129226,0.0002333398,0.0001122463,0.0001028767,0.0001357671],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006513643,0.000103618,0.0007498513,0.00002869667,0.0003297506,0.0000077253,0.0005480985,0.00000549859,0.9301419,0.00005439874,0.04832393,0.01964135],"study_design_scores_gemma":[0.0002419215,0.00006785942,0.0003256983,0.00003927269,0.0001890534,0.0001399049,0.0002111483,0.0009207905,0.5968834,0.0004467226,0.4004155,0.000118761],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9897279,0.001676454,0.00003372065,0.004497012,0.000872482,0.00008571747,0.000008710718,0.00003130743,0.003066732],"genre_scores_gemma":[0.994889,0.001088713,0.0002408344,0.002089749,0.0009480048,0.000005596767,6.2319e-7,0.0000182545,0.0007191956],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3520916,"threshold_uncertainty_score":0.6078163,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04890975802837687,"score_gpt":0.3977508944125628,"score_spread":0.348841136384186,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}