{"id":"W4400387953","doi":"10.1002/anie.202404539","title":"Mechanochemical Synthesis of Boroxine‐linked Covalent Organic Frameworks","year":2024,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Covalent Organic Framework Applications","field":"Materials Science","cited_by":46,"is_retracted":false,"has_abstract":true,"ca_institutions":"Concordia University; McGill University","funders":"Fonds de recherche du Québec – Nature et technologies; Leverhulme Trust; Natural Sciences and Engineering Research Council of Canada; McGill University","keywords":"Mechanochemistry; Mechanosynthesis; Covalent bond; Raman spectroscopy; Crystallinity; Porosity; Chemical engineering; Chemistry; Materials science; Solvent; Nanotechnology; Organic chemistry; Ball mill; Crystallography","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000285367,0.0001679009,0.000186293,0.000129629,0.00004816694,0.0000956255,0.0004341683,0.0003159909,0.01008792],"category_scores_gemma":[0.0005715131,0.0001656628,0.0001216014,0.0002956029,0.0001058438,0.0002574272,0.0001248151,0.0003612552,0.0004722011],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002363313,"about_ca_system_score_gemma":0.00009235489,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001310479,"about_ca_topic_score_gemma":0.000002834713,"domain_scores_codex":[0.9983838,0.00001882447,0.0004152431,0.0004182569,0.0005695453,0.0001943504],"domain_scores_gemma":[0.9987896,0.0004770856,0.0001145349,0.0003068316,0.0002370296,0.00007490328],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000184833,0.00009326997,0.00001601315,0.00007128873,0.00004189123,0.000004998898,0.0001033479,0.000004381723,0.9759255,0.006115139,0.01685643,0.0007492658],"study_design_scores_gemma":[0.00009324868,0.00001441983,0.0000793963,0.0003253262,0.00005676696,0.00002253343,0.00004533847,0.0003372825,0.9808935,0.008963785,0.009011208,0.0001572126],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5591571,0.00157272,0.3897856,0.02363269,0.01269499,0.0007928851,0.001276652,0.001365243,0.009722115],"genre_scores_gemma":[0.9946356,0.0001726513,0.002941908,0.0001936559,0.00145178,0.0001304197,0.0001776988,0.00003592532,0.0002603585],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4354785,"threshold_uncertainty_score":0.990817,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01102862304264934,"score_gpt":0.2645216480401283,"score_spread":0.2534930249974789,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}