{"id":"W4400599042","doi":"10.1002/chem.202401308","title":"Tuning Energetics of 2 e<sup>−</sup>/2H<sup>+</sup> PCET Properties with Model Ru‐bisamido Complexes","year":2024,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Lanthanide and Transition Metal Complexes","field":"Materials Science","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Fondo para la Investigación Científica y Tecnológica; National Institute of General Medical Sciences; National Institutes of Health; Simon Fraser University; Consejo Nacional de Investigaciones Científicas y Técnicas; Foundation for the National Institutes of Health","keywords":"Energetics; Chemistry; Chemical physics; Thermodynamics; Physics","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001726249,0.0002604247,0.0002236265,0.0001227565,0.0001745703,0.0004146935,0.0004689765,0.00028488,0.002916711],"category_scores_gemma":[0.0003329517,0.0001450945,0.00007273119,0.0001255603,0.0002049979,0.0003261048,0.00022307,0.0003219122,0.0002142976],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004995915,"about_ca_system_score_gemma":0.00007934108,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005979093,"about_ca_topic_score_gemma":0.0006983908,"domain_scores_codex":[0.9998877,0.00001524192,0.000005431632,0.0000271381,0.00003780219,0.00002668349],"domain_scores_gemma":[0.9999143,0.00004791842,0.00001341889,0.000005092643,0.00000994252,0.000009309862],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001504162,0.0001886218,0.001375033,0.00029883,0.00003728828,0.0002013117,0.0001062855,0.01207003,0.973065,0.002187393,0.0007705622,0.008195638],"study_design_scores_gemma":[0.00005752619,0.0004114485,0.0008407496,0.000005449689,0.000009600416,0.00003844432,0.00004644267,0.02916872,0.9682514,0.0001076262,0.001050485,0.00001214634],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9973654,0.0001398987,0.000641217,0.00003939605,0.000007022371,0.000008564988,0.00007487951,0.00006521852,0.00165833],"genre_scores_gemma":[0.9992751,0.00005313485,0.000259634,0.000007391582,9.385171e-7,0.000007232913,0.00005041316,0.00001754574,0.0003285295],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002916711,"threshold_uncertainty_score":0.0097574,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03427732099430348,"score_gpt":0.2231693935919736,"score_spread":0.1888920725976701,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}