{"id":"W4400599042","doi":"10.1002/chem.202401308","title":"Tuning Energetics of 2 e<sup>−</sup>/2H<sup>+</sup> PCET Properties with Model Ru‐bisamido Complexes","year":2024,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Lanthanide and Transition Metal Complexes","field":"Materials Science","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Fondo para la Investigación Científica y Tecnológica; National Institute of General Medical Sciences; National Institutes of Health; Simon Fraser University; Consejo Nacional de Investigaciones Científicas y Técnicas; Foundation for the National Institutes of Health","keywords":"Energetics; Chemistry; Chemical physics; Thermodynamics; Physics","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0008513645,0.0003733027,0.0004324828,0.00007575451,0.0003272432,0.0005442796,0.0006319458,0.0000477687,0.0009982008],"category_scores_gemma":[0.00005066759,0.0002635235,0.0001789988,0.0002125968,0.000405152,0.0004117641,0.0001381785,0.0005109697,0.0001069276],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004948538,"about_ca_system_score_gemma":0.000203135,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000005936463,"about_ca_topic_score_gemma":3.481791e-7,"domain_scores_codex":[0.9975216,0.0002332435,0.0006976531,0.0004415669,0.0006062092,0.0004997766],"domain_scores_gemma":[0.9988892,0.00004885679,0.000178759,0.0003821393,0.0002304399,0.0002705844],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001118046,0.00007079148,0.00002441494,0.0005081104,0.00006894132,0.0003745147,0.002170199,0.09936965,0.8958881,0.00009353171,0.001091621,0.0002282697],"study_design_scores_gemma":[0.0007947187,0.0001619345,0.00001600013,0.001270895,0.0001728621,0.001900711,0.001332839,0.3598191,0.6300501,0.0003134479,0.003615204,0.0005521864],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9830434,0.001056235,0.009375777,0.0002289137,0.00007127953,0.00008034923,0.000111447,0.0001696834,0.005862948],"genre_scores_gemma":[0.9922572,0.0001092295,0.005453695,0.0001026301,0.0004997963,0.000003044633,0.00002702289,0.00009261596,0.001454791],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.265838,"threshold_uncertainty_score":0.9999817,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03427732099430348,"score_gpt":0.2231693935919736,"score_spread":0.1888920725976701,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}