{"id":"W4400647526","doi":"10.1016/j.jhazmat.2024.135223","title":"Simultaneous effect of oxygen impurity and flow rate of purge gas on adsorption capacity of and heel buildup on activated carbon during cyclic adsorption-desorption of VOC","year":2024,"lang":"en","type":"article","venue":"Journal of Hazardous Materials","topic":"Catalytic Processes in Materials Science","field":"Materials Science","cited_by":13,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Foundation for Innovation; Ministry of Advanced Education, Government of Alberta; Ford Motor Company","keywords":"Purge; Adsorption; Activated carbon; Desorption; Impurity; Chemistry; Oxygen; Volumetric flow rate; Heel; Breakthrough curve; Chemical engineering; Inorganic chemistry; Waste management; Organic chemistry; Thermodynamics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.003570613,0.0003303398,0.001230673,0.0004414706,0.00004392895,0.00009630113,0.0003236333,0.0001825855,0.00007887034],"category_scores_gemma":[0.001246255,0.0002565906,0.000117357,0.000273861,0.0004409936,0.0003810022,0.0001345825,0.0001478354,0.00000259481],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001197326,"about_ca_system_score_gemma":0.0001111118,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001609762,"about_ca_topic_score_gemma":0.000005268891,"domain_scores_codex":[0.9965631,0.0005095787,0.00158026,0.00039745,0.0006446555,0.0003049756],"domain_scores_gemma":[0.9967052,0.0007622233,0.001733553,0.0003448256,0.0003360037,0.0001182101],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.002778639,0.0001197612,0.00007882604,0.003329929,0.00005080764,0.00002172834,0.0004177142,0.001366235,0.9915159,0.00005974472,0.000005089414,0.0002556192],"study_design_scores_gemma":[0.0009697945,0.001775022,0.001352281,0.001851666,0.0001319962,0.0002284065,0.0000306868,0.0006182494,0.9920883,0.0007607711,0.000003325373,0.0001895395],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9978238,0.0002226229,0.00004390733,0.00004245482,0.001167217,0.000393071,0.0002642458,0.0000271361,0.00001549365],"genre_scores_gemma":[0.9992164,0.0002754051,0.0003012146,0.000007302717,0.0001508389,0.00000608324,0.000003873573,0.00003145454,0.000007388322],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002324359,"threshold_uncertainty_score":0.9999886,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008105477696902293,"score_gpt":0.2452413188121864,"score_spread":0.2371358411152841,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}