{"id":"W4400729552","doi":"10.1002/anie.202411992","title":"Iron(II)‐Catalyzed 1,2‐Diamination of Styrenes Installing a Terminal NH<sub>2</sub> Group Alongside Unprotected Amines","year":2024,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Synthesis and Catalytic Reactions","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Agence Nationale de la Recherche","keywords":"Vicinal; Chemistry; Nucleophile; Functional group; Alkyl; Catalysis; Combinatorial chemistry; Primary (astronomy); Amination; Leaving group; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001111397,0.0003353105,0.000125936,0.0001171158,0.0001169165,0.0001345921,0.0001951595,0.0002294929,0.000984474],"category_scores_gemma":[0.0001238771,0.0001083612,0.0001209,0.00008996576,0.0001429374,0.00019413,0.0001662373,0.0003057375,0.0004444772],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001971198,"about_ca_system_score_gemma":0.0001678007,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003498898,"about_ca_topic_score_gemma":0.001479829,"domain_scores_codex":[0.9999335,0.000008663961,0.000004789679,0.00001892439,0.00001491023,0.0000192777],"domain_scores_gemma":[0.9999424,0.00001044233,0.00001867592,0.000008340782,0.000008852743,0.00001122082],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004039067,0.00001766321,0.00009946509,0.00009149296,0.000005950174,0.00009784779,0.00002691538,0.0001999532,0.9938405,0.0004169318,0.0001854648,0.00497753],"study_design_scores_gemma":[0.000005605382,0.0001540412,0.0004485529,0.000004643375,0.000005807834,0.0001520375,0.000006775466,0.000753189,0.9942206,0.00006391765,0.00418046,0.000004375559],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9488946,0.00343973,0.02816343,0.0001834517,0.0002022461,0.00008803132,0.0002475258,0.0003497854,0.0184312],"genre_scores_gemma":[0.9877578,0.001016468,0.006838067,0.00004243377,0.00002200717,0.00001426614,0.0001334244,0.00002310933,0.00415244],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.000984474,"threshold_uncertainty_score":0.003293335,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01138451887107035,"score_gpt":0.2391315955015972,"score_spread":0.2277470766305268,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}