{"id":"W4400729552","doi":"10.1002/anie.202411992","title":"Iron(II)‐Catalyzed 1,2‐Diamination of Styrenes Installing a Terminal NH<sub>2</sub> Group Alongside Unprotected Amines","year":2024,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Synthesis and Catalytic Reactions","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Agence Nationale de la Recherche","keywords":"Vicinal; Chemistry; Nucleophile; Functional group; Alkyl; Catalysis; Combinatorial chemistry; Primary (astronomy); Amination; Leaving group; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001550427,0.0002406349,0.0002189232,0.0002309485,0.0001147733,0.0001067421,0.000244925,0.0001845095,0.0004546069],"category_scores_gemma":[0.000226985,0.0002393887,0.0002001944,0.0002258211,0.0001103806,0.0006021439,0.00008470925,0.0002173211,0.00002911069],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002332042,"about_ca_system_score_gemma":0.00004769521,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000839429,"about_ca_topic_score_gemma":0.00003512836,"domain_scores_codex":[0.9983064,0.000009702439,0.0004938057,0.0004298184,0.0005562945,0.0002039801],"domain_scores_gemma":[0.9990609,0.0001957724,0.0002086866,0.0002254041,0.0002387628,0.00007051583],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004284446,0.0001669176,0.00005322455,0.0002342563,0.0001264601,0.00003686497,0.0002248493,0.00001208576,0.9750954,0.0003707489,0.0007653754,0.02287096],"study_design_scores_gemma":[0.0003423282,0.00001956737,0.0006253248,0.0005033773,0.00009531122,0.0001221905,0.0002316915,0.0008486272,0.9927029,0.0007596745,0.003510449,0.000238551],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9889799,0.0002910013,0.002282976,0.000502177,0.001025349,0.0001059401,0.0003192394,0.0002256493,0.006267751],"genre_scores_gemma":[0.9947783,0.0001645761,0.0001443904,0.00001982434,0.001769109,0.0001480372,0.002624914,0.00004113195,0.0003097625],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02263241,"threshold_uncertainty_score":0.9761989,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01138451887107035,"score_gpt":0.2391315955015972,"score_spread":0.2277470766305268,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}