{"id":"W4400778585","doi":"10.1039/d4dt01561d","title":"Group 11 complexes of a bulky triazene ligand","year":2024,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Chemical Reactions and Mechanisms","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"Saint Mary's University","funders":"Natural Sciences and Engineering Research Council of Canada; Saint Mary’s University","keywords":"Triazene; Group (periodic table); Ligand (biochemistry); Chemistry; Stereochemistry; Medicinal chemistry; Organic chemistry; Receptor","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00005255281,0.0001139706,0.0001664946,0.0000671572,0.00006891156,0.00003043645,0.00008824854,0.00009715661,0.002560903],"category_scores_gemma":[0.000007332697,0.000106879,0.0001808061,0.0002081044,0.0000431984,0.00008600552,0.000003373913,0.0001847505,0.00003212322],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000410362,"about_ca_system_score_gemma":0.00003502896,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001714001,"about_ca_topic_score_gemma":0.00007451322,"domain_scores_codex":[0.9992532,0.000002748201,0.0002346043,0.0002110294,0.0001394728,0.0001589373],"domain_scores_gemma":[0.9995415,0.0001190227,0.00002665256,0.0002002976,0.00002510028,0.00008742712],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001467562,0.0001212074,0.000001925259,0.0002045092,0.00004974924,0.00000427433,0.0001216097,0.000007526967,0.9862602,0.003938849,0.0001935451,0.009081955],"study_design_scores_gemma":[0.000269471,0.00001575683,0.00000373952,0.00009767194,0.00008678834,0.00002601,0.0001595442,0.000445931,0.895846,0.001079903,0.101866,0.0001032257],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.861208,0.0009000285,0.12416,0.0005131624,0.000576561,0.0001204543,0.0006462737,0.0005282394,0.01134734],"genre_scores_gemma":[0.9962301,0.0001624049,0.0004728389,0.00001399155,0.00008757078,0.00003014505,0.00005585008,0.00002339124,0.002923724],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1350221,"threshold_uncertainty_score":0.9983509,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01790851627979646,"score_gpt":0.2573018378039825,"score_spread":0.2393933215241861,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}