{"id":"W4400839746","doi":"10.1002/zaac.202400083","title":"Reactions of the Geminal Dicarbanion Li<sub>2</sub>[C(SPPh<sub>2</sub>)<sub>2</sub>] with Selenium and Tellurium","year":2024,"lang":"en","type":"article","venue":"Zeitschrift für anorganische und allgemeine Chemie","topic":"Crystallography and molecular interactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Fundamental Research Funds for the Central Universities; Natural Sciences and Engineering Research Council of Canada; National Natural Science Foundation of China","keywords":"Geminal; Selenium; Tellurium; Chemistry; Stereochemistry; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001102427,0.0002789457,0.0001924285,0.0001321798,0.0002396243,0.0002020948,0.0002124556,0.0002542703,0.001786008],"category_scores_gemma":[0.0001891102,0.0001160388,0.00009846453,0.0001343957,0.0002208326,0.0001879877,0.0002572249,0.0001754245,0.0003581055],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002670662,"about_ca_system_score_gemma":0.0001499939,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006251637,"about_ca_topic_score_gemma":0.001874358,"domain_scores_codex":[0.9999064,0.0000251094,0.000006020259,0.00001695336,0.00002056926,0.00002480489],"domain_scores_gemma":[0.9999219,0.00002115971,0.00002006495,0.000009970759,0.0000140135,0.00001290676],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003085944,0.00002087044,0.0003427189,0.0001007941,0.00001298353,0.0001376035,0.00006545675,0.0002735787,0.99577,0.0003745103,0.0001199883,0.002472918],"study_design_scores_gemma":[0.00001273438,0.0002144596,0.0005251446,0.000002432209,0.000005637249,0.0001525991,0.00002097919,0.0003525655,0.9969268,0.00006687977,0.001714248,0.000005543176],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9947923,0.0005448275,0.0009141122,0.00003631952,0.00001825428,0.00001796192,0.00005200994,0.00004990655,0.003574301],"genre_scores_gemma":[0.9962478,0.0002360923,0.0009327418,0.0000219108,0.000003580202,0.000006804423,0.00008998193,0.00001498076,0.002446038],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001786008,"threshold_uncertainty_score":0.00597477,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005120422816797117,"score_gpt":0.2215365990018054,"score_spread":0.2164161761850082,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}