{"id":"W4400871165","doi":"10.1055/a-2370-7112","title":"Chemo- and Regioselective Demethylation of 2-Bromo-α-resorcylic Acid Derivatives Using Alkylthiolate Salts","year":2024,"lang":"en","type":"article","venue":"Synlett","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université du Québec à Rimouski; Université Laval","funders":"Natural Sciences and Engineering Research Council of Canada; Université du Québec à Rimouski; Université Laval","keywords":"Chemistry; Regioselectivity; Demethylation; Organic chemistry; Stereochemistry; Catalysis; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003681064,0.0004965575,0.0003018329,0.0001920655,0.0001151243,0.000111497,0.0003079209,0.0003257552,0.001230725],"category_scores_gemma":[0.0002801637,0.0001289016,0.000224111,0.0001688019,0.0001981835,0.0002126307,0.0002045804,0.0003922463,0.0006051153],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001580096,"about_ca_system_score_gemma":0.0002694846,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004596738,"about_ca_topic_score_gemma":0.001358241,"domain_scores_codex":[0.9997981,0.00005684163,0.00001982654,0.00003996037,0.00003800092,0.00004734602],"domain_scores_gemma":[0.9998808,0.00002508195,0.00003855221,0.00002103974,0.00002027005,0.00001428993],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004908499,0.00001287027,0.00006201972,0.00008314715,0.000008019149,0.0001181735,0.00003296639,0.0001499619,0.9966969,0.00009263941,0.00003966477,0.002654611],"study_design_scores_gemma":[0.000007294986,0.0001449518,0.0002113216,0.000002849368,0.000007545859,0.0001675899,0.000007490778,0.00009798673,0.9981841,0.00001403616,0.001150781,0.000004032653],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9645556,0.004965548,0.02370814,0.0002212227,0.00005783341,0.0001456056,0.0004376401,0.0002363741,0.005671946],"genre_scores_gemma":[0.9857128,0.003269528,0.007830694,0.00005584018,0.00001828226,0.00003340965,0.0002821504,0.00004078811,0.002756446],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001230725,"threshold_uncertainty_score":0.004117131,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.1111709122002485,"score_gpt":0.4445553301795293,"score_spread":0.3333844179792808,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}