{"id":"W4400966082","doi":"10.1002/ange.202410363","title":"Direct Excitation Strategy for Deacylative Couplings of Ketones","year":2024,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Excitation; Chemistry; Combinatorial chemistry; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007162623,0.0001293676,0.0001826051,0.00003390082,0.00003619551,0.0000301689,0.0001042742,0.000126755,0.0005215792],"category_scores_gemma":[0.0002943917,0.0001187701,0.0001427986,0.000146364,0.00009343501,0.000115074,0.00001607289,0.0001268362,0.00001304877],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007705035,"about_ca_system_score_gemma":0.0000651513,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003893492,"about_ca_topic_score_gemma":0.000004070858,"domain_scores_codex":[0.9991891,0.000001870354,0.0002285242,0.0002593021,0.0001447557,0.0001764223],"domain_scores_gemma":[0.998872,0.0007558546,0.00005675414,0.0001534785,0.00008463136,0.00007731905],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002912434,0.00003673026,0.00001991634,0.0004281938,0.00007599726,0.000001668111,0.0001595986,0.000009325584,0.994624,0.0005052789,0.003447209,0.000662959],"study_design_scores_gemma":[0.0001830902,0.00001687548,0.00001671261,0.000146036,0.00005816018,0.000002268763,0.000103949,0.0003406403,0.9763984,0.003291609,0.01931529,0.0001269356],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8213091,0.002138089,0.0005485686,0.0002206744,0.0001267227,0.0002205104,0.0002629664,0.00024279,0.1749306],"genre_scores_gemma":[0.996047,0.00006078259,0.0002754945,0.00001793674,0.0001774649,0.000127367,0.0001408283,0.00003014059,0.003123043],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1747379,"threshold_uncertainty_score":0.5710927,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03482500553491177,"score_gpt":0.3088327845807543,"score_spread":0.2740077790458425,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}