{"id":"W4401101062","doi":"10.1080/00958972.2024.2383986","title":"Tris[dimethylplatinum(2-pyridylmethyliminoethyl)]amine: first structure with the ligand in the tris(bidentate) bonding mode","year":2024,"lang":"en","type":"article","venue":"Journal of Coordination Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Chemistry; Ligand (biochemistry); Tris; Denticity; Amine gas treating; Crystallography; Crystal structure; Stereochemistry; Organic chemistry; Receptor","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0007497321,0.0002612218,0.0003809809,0.0001180298,0.0001774214,0.0003675502,0.0007053358,0.0001470817,0.00221017],"category_scores_gemma":[0.000217366,0.0001455695,0.0002343353,0.0007510391,0.0001040789,0.0002808005,0.00005118895,0.000834319,0.000003735619],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001934137,"about_ca_system_score_gemma":0.0001334663,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002158372,"about_ca_topic_score_gemma":0.00002537462,"domain_scores_codex":[0.9980482,0.00004289517,0.0006477942,0.0002539244,0.0007553977,0.0002517246],"domain_scores_gemma":[0.9980566,0.0009097376,0.0004470049,0.0003638096,0.0001529508,0.00006990365],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002063725,0.0001845481,0.001067037,0.0008539332,0.0006697708,0.000282228,0.004947197,0.0007545743,0.9508457,0.0002363926,0.007310817,0.03264142],"study_design_scores_gemma":[0.001415359,0.00004728915,0.001224806,0.0004947387,0.0006563146,0.001014155,0.007414233,0.001902858,0.8747199,0.0008990238,0.1097289,0.0004824379],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9858698,0.00271386,0.0002134081,0.007817045,0.00008180685,0.00006444638,0.00003546543,0.0000233579,0.003180847],"genre_scores_gemma":[0.9959031,0.00007232438,0.00009383672,0.00005651845,0.0006375185,0.000008857098,0.00002053256,0.00003459872,0.00317274],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1024181,"threshold_uncertainty_score":0.9987019,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009142515209961696,"score_gpt":0.246598964190732,"score_spread":0.2374564489807703,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}