{"id":"W4401526304","doi":"10.1002/ajoc.202400355","title":"A Simple and Facile Conjugate Addition of Cyclic and Acyclic 1,3‐Diketones to β‐Nitrostyrenes","year":2024,"lang":"en","type":"article","venue":"Asian Journal of Organic Chemistry","topic":"Chemical Reaction Mechanisms","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"Algoma University","funders":"","keywords":"Chemistry; Conjugate; Nitro; Pentane; Medicinal chemistry; Diketone; Simple (philosophy); Stereochemistry; Combinatorial chemistry; Organic chemistry; Mathematics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001190003,0.0001904235,0.0003291285,0.00004759759,0.00003946203,0.00007023641,0.0001466097,0.0001467331,0.003156194],"category_scores_gemma":[0.0002844105,0.0001795053,0.00009033806,0.0001669494,0.00007752769,0.000154858,0.00008585148,0.0003291601,0.000009297242],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006993659,"about_ca_system_score_gemma":0.00008874569,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000001772307,"about_ca_topic_score_gemma":0.000001151614,"domain_scores_codex":[0.9988137,0.000007204557,0.0004921471,0.0002366574,0.0002575688,0.0001926845],"domain_scores_gemma":[0.9991246,0.0001110808,0.0002012954,0.0001776871,0.00009541283,0.0002898982],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003864534,0.00002949566,0.0001196238,0.000480316,0.00007805861,0.00004708628,0.0002397432,2.105145e-7,0.990422,0.00001410058,0.0006202633,0.007910436],"study_design_scores_gemma":[0.0003866164,0.00003339281,0.00007116709,0.0003392541,0.00008066127,0.001084116,0.000856449,0.0000121668,0.9868029,0.001166117,0.009003667,0.0001635086],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9967082,0.0008903751,0.0001384377,0.0007175659,0.00005962108,0.00003047827,0.00009048938,0.00003656669,0.001328321],"genre_scores_gemma":[0.9988505,0.0001692766,0.0001964592,0.00003270248,0.0002500562,0.000002338476,0.00001813737,0.00003417138,0.0004463344],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008383404,"threshold_uncertainty_score":0.9977551,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006324297120443423,"score_gpt":0.2330718475390857,"score_spread":0.2267475504186423,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}