{"id":"W4401548123","doi":"10.1021/acssuschemeng.4c05231","title":"Sustainable PLA Bio-Nanocomposites: Integration of TPU Nanofibrils and CNC for Enhanced Crystallization, Toughness, Stiffness, Transparency, and Oxygen Barrier Properties","year":2024,"lang":"en","type":"article","venue":"ACS Sustainable Chemistry & Engineering","topic":"biodegradable polymer synthesis and properties","field":"Materials Science","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Materials science; Thermoplastic polyurethane; Ultimate tensile strength; Fourier transform infrared spectroscopy; Composite material; Toughness; Crystallization; Chemical engineering; Elastomer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001443365,0.0004603744,0.0001462532,0.0001963003,0.0001137559,0.0002350558,0.0001648993,0.0002607621,0.0005843958],"category_scores_gemma":[0.0001639672,0.0001462009,0.000159776,0.0001110736,0.0001300031,0.0003315093,0.0001411981,0.0002458683,0.0001577858],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003252305,"about_ca_system_score_gemma":0.0001779354,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008009737,"about_ca_topic_score_gemma":0.002596724,"domain_scores_codex":[0.9998841,0.000009187722,0.00000724934,0.00003360043,0.00004715174,0.00001856727],"domain_scores_gemma":[0.999878,0.00002376617,0.0000447101,0.000006334476,0.00002629176,0.00002084539],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000126187,0.000007409012,0.00004339106,0.00001843453,0.000001666855,0.00001568792,0.000003770583,0.0001125187,0.9991177,0.00001608247,0.000004802812,0.000645979],"study_design_scores_gemma":[0.000001518506,0.00005536482,0.0007512333,0.000002408723,0.000004607449,0.00003704271,0.000005257032,0.00134728,0.9974664,0.000006453809,0.0003194828,0.000002815905],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9913368,0.001033763,0.005900235,0.00003750787,0.00001375528,0.00002470802,0.00009414904,0.00008811111,0.001470967],"genre_scores_gemma":[0.9900988,0.0004879621,0.008076019,0.00002043223,0.000005522131,0.00002691396,0.00009756394,0.00002282843,0.00116384],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008009737,"threshold_uncertainty_score":0.002359748,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00940280368797368,"score_gpt":0.2003742151368169,"score_spread":0.1909714114488432,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}