{"id":"W4401729753","doi":"10.1116/6.0003804","title":"Interpretation of complex x-ray photoelectron peak shapes. I. Case study of Fe 2p3/2 spectra","year":2024,"lang":"en","type":"article","venue":"Journal of Vacuum Science & Technology A Vacuum Surfaces and Films","topic":"Electron and X-Ray Spectroscopy Techniques","field":"Materials Science","cited_by":29,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Interpretation (philosophy); Spectral line; X-ray; X-ray photoelectron spectroscopy; Crystallography; Materials science; Physics; Chemistry; Nuclear magnetic resonance; Nuclear physics; Computer science; Quantum mechanics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.002110982,0.0002842618,0.0007327009,0.001564375,0.0002342501,0.0001449993,0.0008982001,0.0001703655,0.0001608644],"category_scores_gemma":[0.00007573739,0.0002171181,0.0001185961,0.002121941,0.001137116,0.0007585742,0.0002077434,0.0005762,0.000003153793],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001026895,"about_ca_system_score_gemma":0.0003517545,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001368954,"about_ca_topic_score_gemma":0.00008095137,"domain_scores_codex":[0.9971461,0.00008469326,0.00105755,0.0005100397,0.0006529058,0.0005487577],"domain_scores_gemma":[0.998347,0.000112894,0.000696987,0.000324009,0.0004036454,0.0001154595],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001089091,0.0003492737,0.0008482878,0.0000653591,0.00003850512,0.0003527449,0.001963739,0.00003872397,0.9937474,0.001533893,0.0001195472,0.0008335869],"study_design_scores_gemma":[0.0006072547,0.01019077,0.00130635,0.0002500626,0.0001480544,0.003757803,0.008949473,0.01336867,0.9576825,0.003304013,0.0001206505,0.0003144269],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9945132,0.00243804,0.001712212,0.0004168001,0.0002537156,0.000372336,0.00001234515,0.0001501512,0.0001311804],"genre_scores_gemma":[0.9924005,0.0003111791,0.007178748,0.00002198779,0.00002213115,0.000007607309,3.757911e-7,0.0000204336,0.00003700041],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03606496,"threshold_uncertainty_score":0.8853817,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01465440553339063,"score_gpt":0.3040927080267022,"score_spread":0.2894383024933115,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}