{"id":"W4401813816","doi":"10.1002/cptc.202400216","title":"Experimental and Computational Investigation of the Photophysical Properties of a Series of Luminescent D−A−D’ and D−A−A’ Pyrimidines","year":2024,"lang":"en","type":"article","venue":"ChemPhotoChem","topic":"Organic Light-Emitting Diodes Research","field":"Engineering","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Manitoba","funders":"","keywords":"Excited state; Luminescence; Acceptor; Fluorescence; Photochemistry; Chemistry; Pyrimidine; Character (mathematics); Materials science; Stereochemistry; Optoelectronics; Atomic physics; Physics; Mathematics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000558652,0.00007764361,0.0001316211,0.00003262581,0.00001410847,0.00001141895,0.00006380206,0.00003298281,0.00000553873],"category_scores_gemma":[0.00002262774,0.00005543806,0.00002684087,0.0001341117,0.0003131632,0.00007426846,0.00006820558,0.00005794901,2.596266e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002124828,"about_ca_system_score_gemma":0.00003638125,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001020011,"about_ca_topic_score_gemma":3.11988e-7,"domain_scores_codex":[0.999484,0.00000885248,0.0001746169,0.00009427284,0.0001635807,0.00007467815],"domain_scores_gemma":[0.9997961,0.00002791806,0.00002252751,0.00008540853,0.00004149519,0.00002653809],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00000802926,0.00001111533,0.0008536144,0.001048493,0.00002948872,2.426472e-7,0.002865384,0.00001657375,0.9949512,0.000135622,0.00005803671,0.00002218863],"study_design_scores_gemma":[0.0001122031,0.00002343822,0.0008074584,0.0002633582,0.000007790304,0.000007907097,0.0003161436,0.01129713,0.9870491,0.00005181335,0.0000128448,0.00005082941],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9980718,0.001524569,0.000006981903,0.00005032416,0.00004303979,0.0002050713,0.000005671675,0.00002963562,0.00006286373],"genre_scores_gemma":[0.9996843,0.00001056386,0.0002216918,0.000002896568,0.00002208477,0.00002059123,0.000001684454,0.00001424322,0.00002188655],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01128055,"threshold_uncertainty_score":0.2260699,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01632725646859218,"score_gpt":0.2201803879277015,"score_spread":0.2038531314591093,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}