{"id":"W4401959122","doi":"10.1002/anie.202413782","title":"Unusual Cross‐Conjugation in Cyclic Dipeptide‐Based Building Blocks for Donor–Acceptor Semiconducting Conjugated Polymers","year":2024,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Conducting polymers and applications","field":"Materials Science","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"Ministry of Education and Child Care","funders":"National Natural Science Foundation of China","keywords":"Delocalized electron; Conjugated system; Intramolecular force; Dipeptide; Materials science; Polymer; Acceptor; Aromaticity; Electron acceptor; Chemical physics; Conjugate; Electron; Chemistry; Photochemistry; Molecule; Organic chemistry; Peptide; Physics; Composite material; Condensed matter physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003931847,0.0001913788,0.0001601801,0.0002439651,0.0001607653,0.0003865544,0.0002522092,0.0001258452,0.001197342],"category_scores_gemma":[0.0002032243,0.0002015779,0.0001132402,0.0002676173,0.0001084603,0.0006250534,0.0000446235,0.000170534,0.00003514024],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002723763,"about_ca_system_score_gemma":0.0001123174,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002352546,"about_ca_topic_score_gemma":0.0000329793,"domain_scores_codex":[0.9984232,0.0000183004,0.0004564514,0.0005307568,0.0002775242,0.0002937355],"domain_scores_gemma":[0.9991392,0.0003360729,0.0001472483,0.0001527707,0.0001528458,0.00007178925],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003243694,0.00005393251,0.0002380728,0.0000391789,0.00001635271,0.00000260334,0.0001953781,0.0001679152,0.9954913,0.0006358435,0.001922448,0.001204549],"study_design_scores_gemma":[0.0006038612,0.00002298213,0.0001445267,0.0001727457,0.00002064431,0.000008761393,0.0001599872,0.002163558,0.9880452,0.0008655762,0.007564514,0.0002276021],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9835108,0.0002023523,0.008800553,0.002009854,0.003444884,0.0003337966,0.0003494458,0.0002525076,0.001095803],"genre_scores_gemma":[0.9950238,0.000008170856,0.001159364,0.0002682662,0.001857555,0.0003160942,0.0007199254,0.00003421512,0.0006126291],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01151298,"threshold_uncertainty_score":0.9997157,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02634923779655097,"score_gpt":0.3260308398093937,"score_spread":0.2996816020128428,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}