{"id":"W4402148534","doi":"10.1039/d4cc04014g","title":"A povarov-type reaction to access tetrahydroquinolines from<i>N</i>-benzylhydroxylamines and alkenes in HFIP","year":2024,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Agence Nationale de la Recherche","keywords":"Combinatorial chemistry; Chemistry; Reaction conditions; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009682844,0.0001567851,0.0002203057,0.0001836106,0.00006883042,0.0001437962,0.0008452915,0.0001358302,0.00005908191],"category_scores_gemma":[0.0003679288,0.0001508263,0.00006231899,0.0009824459,0.00008716321,0.0002693338,0.000577311,0.0002584687,0.00004621103],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007771857,"about_ca_system_score_gemma":0.0000301417,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006782057,"about_ca_topic_score_gemma":0.00009815945,"domain_scores_codex":[0.9990191,0.00001928765,0.0003096257,0.00033809,0.000134821,0.0001790763],"domain_scores_gemma":[0.9979489,0.0007435546,0.00003759213,0.00111726,0.00004953635,0.00010316],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001605399,0.0001342503,0.002199398,0.00006764523,0.0000712153,0.000003051569,0.0002672696,0.000001759667,0.919949,0.0004299234,0.001049155,0.07581128],"study_design_scores_gemma":[0.0001898408,0.000007218146,0.001169126,0.000312655,0.000117309,0.00001021006,0.0003184503,0.003620662,0.9077832,0.00188568,0.08418385,0.0004018555],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9730171,0.01079435,0.00003180738,0.00407848,0.00006114325,0.00007004572,0.0000456854,0.0001895488,0.01171183],"genre_scores_gemma":[0.9968839,0.001434117,0.0008023125,0.0001416656,0.000122204,0.00006880274,0.000234313,0.00002689344,0.0002857516],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0831347,"threshold_uncertainty_score":0.6150519,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04102465315453212,"score_gpt":0.3223195542220924,"score_spread":0.2812949010675602,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}