{"id":"W4402191884","doi":"10.1039/d4cp02798a","title":"Cyclopentene and cyclopentadiene formation in isoprene pyrolysis","year":2024,"lang":"en","type":"article","venue":"Physical Chemistry Chemical Physics","topic":"Heat transfer and supercritical fluids","field":"Engineering","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; Secretaria de Ciencia y Tecnología - Universidad Nacional de Córdoba; Ministerio de Ciencia, Tecnología e Innovación Productiva; Consejo Nacional de Investigaciones Científicas y Técnicas; Ministerio de Ciencia, Tecnología e Innovación","keywords":"Isoprene; Cyclopentene; Cyclopentadiene; Pyrolysis; Chemistry; Organic chemistry; Photochemistry; Catalysis; Polymer; Copolymer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00003346076,0.0002287118,0.0002777775,0.00001435923,0.00001894831,0.00007371998,0.0001195474,0.00008383023,0.00003056476],"category_scores_gemma":[0.00001217559,0.0002231164,0.0001026902,0.0002915544,0.00007547151,0.0003519776,0.00003947448,0.0003657207,0.00004310719],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009563911,"about_ca_system_score_gemma":0.000007227752,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000005835727,"about_ca_topic_score_gemma":3.454095e-7,"domain_scores_codex":[0.9989927,0.000006531036,0.0002151893,0.0002758509,0.0001719565,0.0003378027],"domain_scores_gemma":[0.9995622,0.00009252227,7.723437e-7,0.0001586601,0.00001659225,0.0001692558],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00000508816,0.00007091319,0.000009973858,0.0006281134,0.00002127934,0.00001777626,0.000221158,0.000114041,0.9924726,0.0008322066,0.0001495462,0.00545731],"study_design_scores_gemma":[0.0001964546,0.000005213784,0.00002116815,0.00009273316,0.00002742375,0.000009123217,0.00001849079,0.09153407,0.9011979,0.006413256,0.0002410739,0.0002431568],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9851929,0.0003760268,0.004134702,0.0001248364,0.00004161095,0.00007809697,0.00002908069,0.0003177044,0.009705072],"genre_scores_gemma":[0.9992923,0.0001053235,0.00005405536,0.00003251468,0.0003542154,0.00003636679,0.00007161431,0.00004025632,0.0000133501],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.09142003,"threshold_uncertainty_score":0.9098423,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00742356156571729,"score_gpt":0.2187859231676373,"score_spread":0.21136236160192,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}