{"id":"W4402450108","doi":"10.1016/j.chroma.2024.465369","title":"Interrogation of a fluoropolymer dispersion manufactured with a non-fluorinated polymerization aid for targeted and non-targeted fluorinated residuals by liquid chromatography high resolution mass spectrometry","year":2024,"lang":"en","type":"article","venue":"Journal of Chromatography A","topic":"Per- and polyfluoroalkyl substances research","field":"Environmental Science","cited_by":6,"is_retracted":false,"has_abstract":false,"ca_institutions":"Discovery Centre","funders":"Chemours","keywords":"Fluoropolymer; Chemistry; Polymerization; Mass spectrometry; Hydrocarbon; Emulsion polymerization; Gas chromatography; Dispersion polymerization; Dispersion (optics); Chromatography; Organic chemistry; Chemical engineering; Polymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002276807,0.0003648761,0.0001796727,0.0002742577,0.0002459086,0.0003823362,0.0002783102,0.0006166324,0.0006895202],"category_scores_gemma":[0.0003910886,0.0001334547,0.0002070396,0.0001360562,0.000303958,0.000276259,0.0001478761,0.0005270165,0.0002784018],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002638683,"about_ca_system_score_gemma":0.0002099141,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007720841,"about_ca_topic_score_gemma":0.0009819495,"domain_scores_codex":[0.9997048,0.00002077758,0.00001591726,0.00009431196,0.0001285294,0.00003549065],"domain_scores_gemma":[0.9998145,0.00006436395,0.00005362839,0.0000145308,0.00004012588,0.00001285992],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002060168,0.000006189105,0.00005752983,0.000005060788,0.000001462035,0.00001877535,0.000006888765,0.00002742406,0.9994009,0.00001403275,0.000005086398,0.0004362202],"study_design_scores_gemma":[0.000001763336,0.00004767544,0.0004353814,9.902915e-7,0.000003305653,0.00002709045,0.000006331693,0.0003955894,0.9988709,0.000004847576,0.0002039765,0.000001974792],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9905334,0.0004441546,0.007646335,0.00006498194,0.00002191206,0.00001538108,0.00013803,0.0001012522,0.001034497],"genre_scores_gemma":[0.9882851,0.0002972554,0.008697571,0.00004357913,0.000008213005,0.00001633635,0.0001517071,0.00003709375,0.002463078],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007720841,"threshold_uncertainty_score":0.00230664,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004414153405003116,"score_gpt":0.2301671852679444,"score_spread":0.2257530318629413,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}