{"id":"W4402839609","doi":"10.1021/acscatal.4c04400","title":"Direct Deoxygenative Homocoupling of Alcohols to Access C(sp<sup>3</sup>)–C(sp<sup>3</sup>) Bonds via Synergistic Ruthenium/Nickel Catalysis","year":2024,"lang":"en","type":"article","venue":"ACS Catalysis","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Centre in Green Chemistry and Catalysis","funders":"Natural Science Foundation of Qinghai; Fonds Québécois de la Recherche sur la Nature et les Technologies; Natural Sciences and Engineering Research Council of Canada; Canada Foundation for Innovation; National Natural Science Foundation of China; Canada Research Chairs","keywords":"Ruthenium; Catalysis; Nickel; Chemistry; Medicinal chemistry; Photochemistry; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001494001,0.0004861365,0.0002465307,0.0001918638,0.0001198151,0.0002192522,0.0004488189,0.0002688245,0.00135494],"category_scores_gemma":[0.0001637391,0.0002308194,0.0002151758,0.0001759652,0.0002913059,0.0005170511,0.0006151619,0.0005740227,0.0005534416],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002400052,"about_ca_system_score_gemma":0.0001901301,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002190733,"about_ca_topic_score_gemma":0.0007557811,"domain_scores_codex":[0.9998488,0.00001779317,0.000009001607,0.00003393629,0.00004591719,0.00004449895],"domain_scores_gemma":[0.999938,0.00001090857,0.0000186204,0.00001240728,0.00000912294,0.00001092002],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009607938,0.00003728667,0.0002524017,0.0003089828,0.00002562939,0.0003306175,0.00009751538,0.0006284926,0.9783099,0.003287509,0.0004558438,0.01616968],"study_design_scores_gemma":[0.000006036779,0.0001171809,0.000244945,0.000005192448,0.00001286693,0.0002056249,0.00002222338,0.001234681,0.9927207,0.0002491625,0.005173722,0.000007704078],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8910785,0.0100022,0.06504932,0.0004173466,0.0002193112,0.0001591027,0.0003071842,0.0005023808,0.03226455],"genre_scores_gemma":[0.9871394,0.001989993,0.008216313,0.00007744214,0.00002492482,0.00002579068,0.00009660522,0.00003323961,0.002396409],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00135494,"threshold_uncertainty_score":0.004532695,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01684863522604466,"score_gpt":0.280640202828687,"score_spread":0.2637915676026423,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}