{"id":"W4402971053","doi":"10.1021/acs.orglett.4c03035","title":"Exploration of Glycosyl Dithioimidocarbonates in Photoinduced Desulfurative Cross-Coupling Reactions","year":2024,"lang":"en","type":"article","venue":"Organic Letters","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Glycosyl; Coupling reaction; Combinatorial chemistry; Coupling (piping); Photochemistry; Computational chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002310497,0.0001840765,0.000203213,0.0001979776,0.00004859398,0.00008797739,0.0001830698,0.0001339752,0.00049352],"category_scores_gemma":[0.0002757191,0.0001870249,0.00008107585,0.0004334574,0.0000907234,0.0005815703,0.000036308,0.0003347821,0.00003385243],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003248543,"about_ca_system_score_gemma":0.00008561169,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001309655,"about_ca_topic_score_gemma":0.00003842525,"domain_scores_codex":[0.99875,0.00001545492,0.0004279661,0.0003615099,0.0002224411,0.0002226323],"domain_scores_gemma":[0.9991105,0.0003868026,0.0001016569,0.0003199136,0.00004398533,0.00003719339],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001888117,0.00003683571,0.0005769105,0.0001253694,0.00003409967,0.00003455852,0.0007903362,0.00005871798,0.9977226,0.000117978,0.0001513769,0.0003323701],"study_design_scores_gemma":[0.0001553991,0.000008753133,0.0001424919,0.00034387,0.00001805602,0.000005938517,0.0002919736,0.001042969,0.9972459,0.0003613756,0.0002003574,0.0001829332],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.99669,0.000101356,0.0007501657,0.001046756,0.0001358192,0.0000969735,0.00001242888,0.0004143454,0.0007521025],"genre_scores_gemma":[0.9991317,0.00003237095,0.0004232875,0.0001071361,0.0001060753,0.00007031349,0.00002262445,0.00005936404,0.0000470657],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00244171,"threshold_uncertainty_score":0.7626653,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02646636232772858,"score_gpt":0.2855745073590399,"score_spread":0.2591081450313113,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}