{"id":"W4403108182","doi":"10.3390/molecules29194688","title":"Synthesis of an Ethylenediaminetetraacetic Acid-like Ligand Based on Sucrose Scaffold and Complexation and Proton Relaxivity Studies of Its Gadolinium(III) Complex in Solution","year":2024,"lang":"en","type":"article","venue":"Molecules","topic":"Lanthanide and Transition Metal Complexes","field":"Materials Science","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada; European Regional Development Fund; Région Normandie; Institut Carnot Santé Animale; Université de Rouen; Centre National de la Recherche Scientifique; Agence Nationale de la Recherche; Indian National Science Academy","keywords":"Gadolinium; Ethylenediaminetetraacetic acid; Ligand (biochemistry); Chemistry; Proton; Scaffold; Sucrose; Chelation; Nuclear chemistry; Combinatorial chemistry; Inorganic chemistry; Organic chemistry; Biomedical engineering; Biochemistry; Medicine","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001268412,0.0003164562,0.0002403368,0.0001671262,0.0001453713,0.0001386751,0.0002313831,0.000202756,0.0009192878],"category_scores_gemma":[0.00009823187,0.0001185395,0.0001610146,0.0002159519,0.000116926,0.0001490799,0.0001766806,0.0002310766,0.0004566468],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002587437,"about_ca_system_score_gemma":0.0003434588,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008484368,"about_ca_topic_score_gemma":0.001541601,"domain_scores_codex":[0.9999444,0.00001075576,0.00000532284,0.00001216397,0.00001352988,0.00001367856],"domain_scores_gemma":[0.9999565,0.000005452101,0.000009309047,0.000003758183,0.0000110495,0.00001394174],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003839481,0.00001320644,0.0000544229,0.00008717964,0.000005231745,0.00006794129,0.00001905907,0.0002928827,0.9963884,0.0003359675,0.0001000869,0.002597291],"study_design_scores_gemma":[0.0000117047,0.0003026107,0.000376872,0.00000676222,0.000009748377,0.0002164455,0.00001779957,0.001534653,0.9905922,0.00004903271,0.006866068,0.00001606134],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.963843,0.001370106,0.02937167,0.0001549708,0.00004186924,0.0001281031,0.0006387205,0.0002938407,0.004157817],"genre_scores_gemma":[0.9596675,0.0008642559,0.03181882,0.00008038825,0.000008708748,0.0001210228,0.0009667648,0.00004560848,0.006427004],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009192878,"threshold_uncertainty_score":0.003075302,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04887854490393721,"score_gpt":0.3033561195887698,"score_spread":0.2544775746848326,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}