{"id":"W4403247643","doi":"10.1002/chem.202403232","title":"Unprecedented Cubic Mesomorphic Behaviour of Crown‐Ether Functionalized Amphiphilic Cyclodextrins","year":2024,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Liquid Crystal Research Advancements","field":"Materials Science","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta; Simon Fraser University; University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada; University of Alberta; Government of Alberta","keywords":"Thermotropic crystal; Mesophase; Amphiphile; Supramolecular chemistry; Materials science; Lithium (medication); Ether; Phase (matter); Copolymer; Crystallography; Liquid crystal; Polymer chemistry; Side chain; Organic chemistry; Chemical engineering; Chemistry; Crystal structure; Liquid crystalline; Polymer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.001507493,0.0002266315,0.0002334842,0.00008308259,0.0001623434,0.0002975714,0.0006310924,0.00003643437,0.019001],"category_scores_gemma":[0.0002639834,0.0001933402,0.0001808216,0.0002896395,0.0002331447,0.0003283301,0.0002199648,0.0005167883,0.000496893],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001796466,"about_ca_system_score_gemma":0.0001975391,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000004290278,"about_ca_topic_score_gemma":3.757316e-7,"domain_scores_codex":[0.9973973,0.000296673,0.0005994961,0.0003857772,0.0008437329,0.0004770384],"domain_scores_gemma":[0.9988009,0.00007917718,0.0001886162,0.0003505898,0.0002352766,0.0003453952],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001523621,0.0001004621,0.0001280071,0.0001421164,0.00004194163,0.0005390173,0.0001350911,0.0000493867,0.9955952,0.00002699119,0.002407152,0.0006823207],"study_design_scores_gemma":[0.002339088,0.0002306308,0.001187018,0.0009490597,0.0001131347,0.002126336,0.0002037316,0.0006896477,0.8958514,0.0010137,0.09472847,0.0005677729],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.990966,0.001411533,0.001132894,0.0002895924,0.0004258447,0.0001061271,0.00006170738,0.0001140051,0.005492357],"genre_scores_gemma":[0.989854,0.000109277,0.0003910902,0.00004210574,0.0004347085,0.000005936663,0.00002090338,0.00007036262,0.009071623],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.09974374,"threshold_uncertainty_score":0.9818957,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02650220639695567,"score_gpt":0.2872151899075881,"score_spread":0.2607129835106324,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}