{"id":"W4403281775","doi":"","title":"Exploring irreversible luminescence thermal transitions of polymetallic copper(I) coordination polymers built from polyphosphines synthons","year":2024,"lang":"en","type":"article","venue":"HAL (Le Centre pour la Communication Scientifique Directe)","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Synthon; Luminescence; Copper; Polymer; Thermal; Materials science; Nanotechnology; Chemistry; Optoelectronics; Metallurgy; Thermodynamics; Composite material; Organic chemistry; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009508021,0.0002306045,0.000097925,0.00009896135,0.0001315309,0.0003271941,0.0002507018,0.0001837248,0.002500131],"category_scores_gemma":[0.0002318303,0.0001137065,0.0001186046,0.0001197672,0.0002529511,0.0003006846,0.0002037139,0.0004701624,0.0002136324],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003032416,"about_ca_system_score_gemma":0.0001205965,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004955232,"about_ca_topic_score_gemma":0.0006721017,"domain_scores_codex":[0.9999242,0.000007498707,0.000002017559,0.00002201075,0.00001536289,0.00002890776],"domain_scores_gemma":[0.9999309,0.00002923101,0.00001983602,0.000006393562,0.000006233406,0.000007538647],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002671211,0.0000459,0.0002702668,0.0002394637,0.000008378117,0.0001056025,0.0001135685,0.001500536,0.9876832,0.001437718,0.0002889505,0.008039231],"study_design_scores_gemma":[0.00001094363,0.0001900434,0.0006214121,0.000007530691,0.000005600226,0.00003697662,0.00002909059,0.002315265,0.9957417,0.00008483007,0.0009503906,0.000006188436],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9944432,0.0003560295,0.001645453,0.00004519366,0.00001023744,0.000009206778,0.00006849709,0.00006992964,0.003352285],"genre_scores_gemma":[0.9980804,0.000220594,0.0006203832,0.00001261164,0.000002925815,0.000009187675,0.00004008196,0.00002191948,0.0009918925],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002500131,"threshold_uncertainty_score":0.008363724,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02656144310838317,"score_gpt":0.2261687137129604,"score_spread":0.1996072706045772,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}