{"id":"W4403353157","doi":"10.1021/acs.analchem.4c02479","title":"Laminar Flow Infrared Spectroelectrochemistry","year":2024,"lang":"en","type":"article","venue":"Analytical Chemistry","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"Centre hospitalier de l'Université Laval; University of Saskatchewan; Université Laval","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Fourier transform infrared spectroscopy; Ascorbic acid; Attenuated total reflection; Ferrocyanide; Electrode; Analytical Chemistry (journal); Laminar flow; Infrared; Infrared spectroscopy; Chemical engineering; Organic chemistry; Optics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00008840067,0.0003388362,0.000337891,0.00002950904,0.0001111159,0.0001965623,0.0004444636,0.0002977537,0.009042335],"category_scores_gemma":[0.00009081189,0.0003147271,0.0004136222,0.0005912784,0.0001544337,0.00008773563,0.00009435178,0.0007625096,0.0004827153],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001920308,"about_ca_system_score_gemma":0.0001292059,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000003510655,"about_ca_topic_score_gemma":4.96914e-7,"domain_scores_codex":[0.9977779,0.000004197721,0.0004290131,0.0007782294,0.0003818692,0.0006287929],"domain_scores_gemma":[0.9988125,0.0001501442,0.0000430601,0.0006276768,0.00005609346,0.000310547],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001141023,0.0001065917,0.00005761447,0.0004484136,0.0002382761,0.00006202244,0.00001624516,0.000009544179,0.9799784,0.001208872,0.01599301,0.001869584],"study_design_scores_gemma":[0.000114791,0.000005406857,0.000002430382,0.00008110631,0.0002072767,0.00006581009,0.0000295272,0.06702363,0.8153279,0.004658962,0.1121184,0.0003647534],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.2253763,0.00286526,0.002591818,0.001650304,0.00002575398,0.00005094401,0.00007000918,0.001143952,0.7662257],"genre_scores_gemma":[0.9161841,0.000133934,0.0004468172,0.0001118116,0.0008905666,0.00005298933,0.0003887159,0.00005612624,0.08173496],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.6908078,"threshold_uncertainty_score":0.9999305,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006001127923199173,"score_gpt":0.2368399236794305,"score_spread":0.2308387957562313,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}