{"id":"W4403424651","doi":"10.1021/acs.inorgchem.4c03642","title":"Innovative <i>N</i>-Acridine Thiosemicarbazones and Their Zn(II) Complexes Transmetallate with Cu(II): Redox Activity and Suppression of Detrimental Oxy-Myoglobin Oxidation","year":2024,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Synthesis and Characterization of Heterocyclic Compounds","field":"Chemistry","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"Discovery Centre","funders":"National Health and Medical Research Council; Türkiye Bilimsel ve Teknolojik Araştırma Kurumu; Tour de Cure; Griffith University; Australian Research Council; National Breast Cancer Foundation; Thrasher Research Fund","keywords":"Chemistry; Myoglobin; Redox; Acridine; Oxidation reduction; Inorganic chemistry; Photochemistry; Medicinal chemistry; Organic chemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007993705,0.0002963448,0.0003496663,0.00003897537,0.0001706083,0.0000666278,0.0001404666,0.0001549719,0.0005292012],"category_scores_gemma":[0.00002077735,0.0002335742,0.00004430082,0.0002569941,0.0001839577,0.0002154679,0.0001800587,0.0002290888,5.615232e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005289118,"about_ca_system_score_gemma":0.00005554575,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002306363,"about_ca_topic_score_gemma":0.000002331091,"domain_scores_codex":[0.998837,0.00001393588,0.0003087943,0.0004611899,0.0001876787,0.0001914085],"domain_scores_gemma":[0.9993359,0.0001136207,0.0001475449,0.0002596652,0.00007168257,0.00007158943],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001157711,0.0001059583,0.0006452169,0.0005246697,0.000129678,0.000003823864,0.0008444836,2.428877e-7,0.993589,0.00001109651,0.00005929323,0.003970778],"study_design_scores_gemma":[0.0004823664,0.00004170196,0.0009753183,0.0004030215,0.00004247188,0.0001204496,0.0003536986,0.0001961261,0.9957886,0.0000470976,0.001289508,0.0002596649],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9976635,0.0006389006,0.00006981501,0.0003005979,0.00003639876,0.00007052276,0.0001292011,0.0001153608,0.0009756983],"genre_scores_gemma":[0.9991674,0.0001686278,0.00007278482,0.00001674308,0.00008740089,0.00001057038,0.0001233626,0.00003834756,0.000314703],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003711113,"threshold_uncertainty_score":0.952488,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007591222618172035,"score_gpt":0.2158256965134052,"score_spread":0.2082344738952332,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}