{"id":"W4403482109","doi":"10.1016/j.fuel.2024.133398","title":"Analytical and numerical estimations of isosteric heat of adsorption with application to hydrogen purification","year":2024,"lang":"en","type":"article","venue":"Fuel","topic":"Carbon Dioxide Capture Technologies","field":"Engineering","cited_by":12,"is_retracted":false,"has_abstract":false,"ca_institutions":"Université du Québec à Trois-Rivières","funders":"National Key Research and Development Program of China; Bureau of Science and Technology of Zhoushan; Wuhan Municipal Science and Technology Bureau; Ministry of Science and Technology of the People's Republic of China; National Natural Science Foundation of China","keywords":"Adsorption; Hydrogen; Thermodynamics; Chemistry; Chromatography; Physical chemistry; Organic chemistry; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00003543273,0.00005957365,0.000101129,0.0001289808,0.000002143717,0.000007889428,0.00004827924,0.00004601747,0.000004056874],"category_scores_gemma":[0.00001805895,0.00005298624,0.00001626055,0.0003855697,0.00003275543,0.00005224605,0.00001374283,0.00004999912,0.000008244937],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002626977,"about_ca_system_score_gemma":0.000006398715,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000007488006,"about_ca_topic_score_gemma":0.000002326177,"domain_scores_codex":[0.9996239,0.00000340374,0.0001312361,0.0001026884,0.00007914359,0.00005962366],"domain_scores_gemma":[0.9997553,0.00002603379,0.000009115231,0.0001611435,0.00002415094,0.00002422887],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"simulation_or_modeling","study_design_scores_codex":[0.00002869631,0.0000525942,0.002547478,0.001099188,0.0001286718,0.000002114367,0.0008098495,0.09471631,0.8400279,0.02479302,0.0005524215,0.03524179],"study_design_scores_gemma":[0.0001005862,0.0001006595,0.01008632,0.00008758665,0.00007027293,0.00002087668,0.0000755284,0.9106935,0.07635818,0.001239986,0.001023495,0.0001429849],"study_design_candidate":"simulation_or_modeling","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7303267,0.0008530559,0.2673817,0.0003207749,0.00002202334,0.0002122899,0.00000980588,0.0003851172,0.0004885405],"genre_scores_gemma":[0.9957906,0.00001894348,0.004104938,0.000004340409,0.000009715695,0.00004337893,0.000009471101,0.00001177072,0.000006856906],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.8159772,"threshold_uncertainty_score":0.2160716,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007047031016159795,"score_gpt":0.2222004626785004,"score_spread":0.2151534316623406,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}