{"id":"W4403553086","doi":"10.1002/anie.202416967","title":"Imidazolate‐Stabilized Cu(III): Dioxygen to Oxides at Type 3 Copper Sites","year":2024,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of the Fraser Valley","funders":"National Institute of General Medical Sciences; National Institutes of Health","keywords":"Chemistry; Imidazolate; Deprotonation; Imidazole; Copper; Denticity; Copper protein; Histidine; Redox; Photochemistry; Combinatorial chemistry; Stereochemistry; Inorganic chemistry; Organic chemistry; Metal; Enzyme","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.0002266638,0.0002737922,0.0002170788,0.0001998451,0.0001023622,0.0001875605,0.0003647674,0.0001863319,0.01945371],"category_scores_gemma":[0.0003070182,0.0002688453,0.0001667571,0.000285334,0.00004139927,0.0004256423,0.0002024631,0.0002070848,0.001814374],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006081456,"about_ca_system_score_gemma":0.00006674136,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004331435,"about_ca_topic_score_gemma":0.00003751142,"domain_scores_codex":[0.9979899,0.00001157466,0.0004203985,0.0005920978,0.0007025079,0.0002835157],"domain_scores_gemma":[0.998888,0.0001670897,0.00008974425,0.0003219792,0.0003499549,0.000183241],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001130817,0.00004422783,0.00007741975,0.00007365688,0.0001554768,0.00002681041,0.0002997231,0.00002610979,0.9329667,0.0009985593,0.06479064,0.0004275666],"study_design_scores_gemma":[0.000395536,0.00001397259,0.00005445023,0.0001129738,0.00004148436,0.00003952677,0.00008915576,0.0004316991,0.8981145,0.001327254,0.09910066,0.0002788131],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9387635,0.0006296271,0.001842878,0.003045253,0.00422357,0.0002273259,0.0005691416,0.0007255146,0.04997319],"genre_scores_gemma":[0.9770747,0.0001066503,0.0008184946,0.0004208931,0.00230334,0.0001088564,0.003677495,0.00006845453,0.01542116],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03831116,"threshold_uncertainty_score":0.9999764,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02296706935551602,"score_gpt":0.2804225908843015,"score_spread":0.2574555215287855,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}