{"id":"W4403637630","doi":"10.1021/acs.inorgchem.4c03498","title":"The H<sub>2</sub>S<i><sub>x</sub></i>macropa Series: Increasing the Chemical Softness of H<sub>2</sub>macropa with Sulfur Atoms to Chelate Radiometals [<sup>213</sup>Bi]Bi<sup>3+</sup> and [<sup>203</sup>Pb]Pb<sup>2+</sup> for Radiopharmaceutical Applications","year":2024,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Radiopharmaceutical Chemistry and Applications","field":"Medicine","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University; TRIUMF","funders":"National Institute of Biomedical Imaging and Bioengineering; Social Sciences and Humanities Research Council of Canada; National Research Council Canada; Canadian Institutes of Health Research; Natural Sciences and Engineering Research Council of Canada; Canada Research Coordinating Committee; National Science Foundation","keywords":"Chemistry; Sulfur; Series (stratigraphy); Chelation; Crystallography; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","research_integrity"],"consensus_categories":["metaepi_narrow","sts","research_integrity"],"category_scores_codex":[0.002272227,0.002230975,0.002395456,0.0002680087,0.001690741,0.0007577767,0.002156167,0.001325566,0.0001482477],"category_scores_gemma":[0.001241239,0.00177348,0.001009192,0.00376758,0.003199724,0.0006358653,0.0009294759,0.003521107,0.0002155849],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001057769,"about_ca_system_score_gemma":0.001577034,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000204198,"about_ca_topic_score_gemma":0.000002002047,"domain_scores_codex":[0.9887129,0.0003059168,0.0028704,0.003259887,0.00197428,0.002876626],"domain_scores_gemma":[0.9896755,0.003193342,0.0006365312,0.003132088,0.0009496195,0.00241292],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001889195,0.0007487178,0.0002263028,0.003381638,0.001565854,0.000146583,0.001656268,0.001329417,0.9752082,0.0003051416,0.002940663,0.01060208],"study_design_scores_gemma":[0.004498217,0.0001974746,0.00004906035,0.0009024856,0.00255183,0.004528331,0.001938452,0.01877725,0.9389505,0.0004945586,0.02528382,0.001827982],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9762956,0.005731099,0.002652595,0.008225229,0.00009077675,0.004360125,0.001155876,0.0008863301,0.0006023653],"genre_scores_gemma":[0.9884335,0.002374802,0.0007762047,0.001275075,0.002593373,0.002887077,0.0007667998,0.000624419,0.0002687883],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03625761,"threshold_uncertainty_score":0.9999709,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01245262687578397,"score_gpt":0.2717432446876041,"score_spread":0.2592906178118201,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}