{"id":"W4403637630","doi":"10.1021/acs.inorgchem.4c03498","title":"The H<sub>2</sub>S<i><sub>x</sub></i>macropa Series: Increasing the Chemical Softness of H<sub>2</sub>macropa with Sulfur Atoms to Chelate Radiometals [<sup>213</sup>Bi]Bi<sup>3+</sup> and [<sup>203</sup>Pb]Pb<sup>2+</sup> for Radiopharmaceutical Applications","year":2024,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Radiopharmaceutical Chemistry and Applications","field":"Medicine","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University; TRIUMF","funders":"National Institute of Biomedical Imaging and Bioengineering; Social Sciences and Humanities Research Council of Canada; National Research Council Canada; Canadian Institutes of Health Research; Natural Sciences and Engineering Research Council of Canada; Canada Research Coordinating Committee; National Science Foundation","keywords":"Chemistry; Sulfur; Series (stratigraphy); Chelation; Crystallography; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00004988536,0.0002482848,0.0001406025,0.00008059703,0.0000770822,0.0001230652,0.0001433837,0.0001251728,0.001076505],"category_scores_gemma":[0.00005954488,0.00010159,0.0000922885,0.00005999808,0.0001503542,0.0001097823,0.0001394007,0.0001748277,0.0002516888],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000141217,"about_ca_system_score_gemma":0.0001165335,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003663405,"about_ca_topic_score_gemma":0.001000363,"domain_scores_codex":[0.9999694,0.000004445314,0.000002645901,0.000008061224,0.000008831528,0.000006631386],"domain_scores_gemma":[0.999966,0.000004629685,0.00001143747,0.00000294822,0.000005416994,0.000009576303],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000175833,0.00001720326,0.0002006633,0.00004568011,0.000007064445,0.00004358906,0.00002092452,0.0002010828,0.9962681,0.00009695154,0.0001005379,0.002822478],"study_design_scores_gemma":[0.00001344045,0.0005163226,0.00184453,0.000002972258,0.00001212813,0.00008338159,0.00001155631,0.0004913633,0.9946996,0.0000153676,0.002304802,0.000004681212],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9964233,0.0005493975,0.001063956,0.00002355894,0.00001396497,0.00002229389,0.00008785188,0.00005764787,0.001757836],"genre_scores_gemma":[0.9931493,0.0007042838,0.00264432,0.00007114673,0.0000110233,0.0000433443,0.000166967,0.0000215477,0.003188046],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001076505,"threshold_uncertainty_score":0.003601313,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01245262687578397,"score_gpt":0.2717432446876041,"score_spread":0.2592906178118201,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}