{"id":"W4403738369","doi":"10.1021/jacs.4c12272","title":"Pinwheel-like Curved Aromatics from the Cyclotrimerization of Strained Alkyne Cycloparaphenylenes","year":2024,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Synthesis and Properties of Aromatic Compounds","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"Impact","funders":"Division of Chemistry","keywords":"Chemistry; Alkyne; Photochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006457268,0.0002183528,0.00009752112,0.0001288907,0.000101264,0.000153734,0.0002050153,0.0001650845,0.001430328],"category_scores_gemma":[0.0001232724,0.0001111896,0.0001009076,0.0001157602,0.0001503211,0.0002424468,0.0002221284,0.0003157164,0.0002875663],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002091296,"about_ca_system_score_gemma":0.0001196836,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003927394,"about_ca_topic_score_gemma":0.001235495,"domain_scores_codex":[0.9999431,0.000005903583,0.000004194763,0.00001286805,0.00001723192,0.00001662482],"domain_scores_gemma":[0.9999517,0.000008140917,0.00001475978,0.000009599255,0.000006496172,0.000009366637],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002370274,0.000009548355,0.00007798251,0.00005699346,0.000004482353,0.00009763036,0.00003174833,0.0003793054,0.9960126,0.0007043245,0.00007018818,0.002531558],"study_design_scores_gemma":[0.000003248847,0.00006909941,0.0007905925,0.000002926982,0.000002994711,0.0001049618,0.000009761336,0.0008111002,0.9955225,0.0000623184,0.002616186,0.000004337639],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9887185,0.0006080884,0.005350477,0.00007083188,0.00002516376,0.00003687256,0.000147523,0.0001119929,0.004930599],"genre_scores_gemma":[0.9930627,0.0004959354,0.003837176,0.0000337741,0.000003913591,0.00002153473,0.0001060028,0.00002641637,0.002412535],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001430328,"threshold_uncertainty_score":0.004784942,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01378197498561203,"score_gpt":0.2372554495511438,"score_spread":0.2234734745655318,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}