{"id":"W4403788280","doi":"10.1139/cjc-2024-0091","title":"Concentration-dependent nonradiative decay mechanisms in fluorescence self-quenching: insights from azulene and 1,3-dichloroazulene","year":2024,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Photochromic and Fluorescence Chemistry","field":"Materials Science","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Azulene; Quenching (fluorescence); Fluorescence; Photochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002118529,0.0002121267,0.0002962518,0.00005053346,0.00009237276,0.0002445423,0.0003544148,0.000180861,0.0006867755],"category_scores_gemma":[0.00008308054,0.0001982444,0.00005912235,0.000149644,0.0001581438,0.0003805916,0.00002403292,0.0004170576,0.00001576755],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004932677,"about_ca_system_score_gemma":0.001958334,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001413509,"about_ca_topic_score_gemma":0.000621438,"domain_scores_codex":[0.9985188,0.00003196005,0.0004953803,0.0003358577,0.0002658316,0.0003521637],"domain_scores_gemma":[0.9987646,0.0001049423,0.0001569338,0.0001613478,0.0000984604,0.0007137405],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001131864,0.000013312,0.0001516209,0.00006934946,0.00002057518,0.00117454,0.001760095,0.00001325352,0.9962919,0.0001125429,0.0001661017,0.0002154181],"study_design_scores_gemma":[0.0003610975,0.00001755442,0.0002560014,0.0004696547,0.00002311715,0.0002542411,0.0004108851,0.0004606939,0.9947755,0.002581179,0.0001747809,0.0002153199],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9934648,0.004405915,0.0002728722,0.0001769528,0.0004062198,0.00007990085,0.00008511303,0.00002102603,0.001087255],"genre_scores_gemma":[0.9981148,0.0001661951,0.001297339,0.00006685664,0.0002612752,0.000007607502,0.00001070914,0.00001895367,0.00005632808],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004649991,"threshold_uncertainty_score":0.8084171,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006066394486569468,"score_gpt":0.2040269816771119,"score_spread":0.1979605871905424,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}