{"id":"W4403893689","doi":"10.1002/anie.202410154","title":"Hydroaminoalkylation for Amine Functionalization of Vinyl‐Terminated Polyethylene Enables Direct Access to Responsive Functional Materials","year":2024,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Antimicrobial agents and applications","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary; Nova Chemicals (Canada); University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; NOVA Chemicals","keywords":"Amine gas treating; Surface modification; Polyethylene; Polymer; Materials science; Polymer chemistry; Catalysis; Differential scanning calorimetry; Chemistry; Functional group; Combinatorial chemistry; Organic chemistry; Chemical engineering","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001248732,0.000288825,0.00008037046,0.0001309182,0.00007768064,0.0001260681,0.0002224732,0.0001948146,0.001485236],"category_scores_gemma":[0.0001938278,0.0001084191,0.0001438102,0.0001024188,0.0001470195,0.000288089,0.0001723964,0.0003204589,0.0004118269],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00010728,"about_ca_system_score_gemma":0.00007152944,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001011926,"about_ca_topic_score_gemma":0.0002605275,"domain_scores_codex":[0.9999106,0.00001330888,0.000007871664,0.00001936209,0.00003170403,0.00001712339],"domain_scores_gemma":[0.9998926,0.00002957509,0.00004141244,0.00001370269,0.00001331723,0.000009390634],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001159456,0.000006603294,0.00004711632,0.00004032948,0.000002324995,0.00003850906,0.00001007395,0.00003829459,0.9977239,0.0001658638,0.00002562625,0.001889825],"study_design_scores_gemma":[0.000001500676,0.00006308367,0.0004086436,0.00000246837,0.000003042494,0.0001136791,0.000003564667,0.0002502409,0.9967366,0.00003120036,0.002383935,0.000001858579],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.95898,0.002703761,0.03068933,0.0001588493,0.00008028746,0.00006415742,0.0002383881,0.0001440808,0.006941132],"genre_scores_gemma":[0.9839389,0.001838058,0.01042093,0.00005670788,0.00002205222,0.00002451659,0.0002218152,0.00003987767,0.003437183],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001485236,"threshold_uncertainty_score":0.004968584,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02690701999287437,"score_gpt":0.2947228275797574,"score_spread":0.267815807586883,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}