{"id":"W4404057830","doi":"10.1021/jacs.4c08329","title":"Impurities in Arylboronic Esters Induce Persistent Afterglow","year":2024,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Luminescence and Fluorescent Materials","field":"Materials Science","cited_by":37,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"British Columbia Knowledge Development Fund; Natural Sciences and Engineering Research Council of Canada; Canada Foundation for Innovation; Julius-Maximilians-Universität Würzburg; University of British Columbia; Canada Research Chairs; China Scholarship Council","keywords":"Chemistry; Afterglow; Impurity; Organic chemistry; Astrophysics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004614952,0.0001262718,0.0003025131,0.00002300991,0.00003780851,0.0001353932,0.0005000524,0.00004161942,0.00007628835],"category_scores_gemma":[0.00004661109,0.00007578821,0.000514014,0.0002160635,0.0004067771,0.0002236534,0.0001467679,0.0002542171,0.00001851161],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002917273,"about_ca_system_score_gemma":0.0001342382,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005505914,"about_ca_topic_score_gemma":0.000001372633,"domain_scores_codex":[0.9987559,0.00005912649,0.0004037635,0.0001540938,0.0003493882,0.0002776723],"domain_scores_gemma":[0.9994313,0.00007485088,0.0002178589,0.0001647968,0.00004108853,0.00007009567],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003160936,0.00003866389,0.001103672,0.00004849628,0.00002279422,0.00001063638,0.001247353,0.00000913987,0.9924576,0.000008200713,0.004653655,0.0003681671],"study_design_scores_gemma":[0.000243662,0.0000938618,0.002423409,0.0004235078,0.00005751203,0.0001470988,0.001911079,0.00009874156,0.9925174,0.0001569317,0.00174792,0.0001788944],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9956332,0.0006735304,0.00000701068,0.002765917,0.0008078495,0.00005669316,0.000006431161,0.00001684127,0.0000325301],"genre_scores_gemma":[0.9981439,0.0001728422,0.0005367671,0.000683492,0.0003899948,0.000002735711,3.406816e-7,0.00001317384,0.00005677087],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002905735,"threshold_uncertainty_score":0.3090554,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01084752382541956,"score_gpt":0.2488448468035237,"score_spread":0.2379973229781041,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}