{"id":"W4404062869","doi":"10.1021/acs.langmuir.4c03265","title":"Comparison of Au Nanoparticle/Poly(9-vinylcarbazole) Thin-Film Electrogeneration at 3 Distinct Liquid/Liquid Interfaces: Water/1,2-Dichloroethane, /α,α,α-Trifluorotoluene, Or/Ionic Liquid","year":2024,"lang":"en","type":"article","venue":"Langmuir","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland","funders":"Memorial University of Newfoundland; Canadian Network for Research and Innovation in Machining Technology, Natural Sciences and Engineering Research Council of Canada","keywords":"1,2-Dichloroethane; Ionic liquid; Liquid liquid; Nanoparticle; Chemical engineering; Materials science; Dichloroethane; Chemistry; Nanotechnology; Polymer chemistry; Organic chemistry; Chromatography; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000124355,0.0003007711,0.0001534646,0.0001565768,0.0000878302,0.0003024772,0.0002705573,0.0003334129,0.0005975232],"category_scores_gemma":[0.0001684601,0.0001497795,0.0001509173,0.0001370872,0.0001399445,0.0002291464,0.0001417583,0.0003232182,0.0001245682],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002036721,"about_ca_system_score_gemma":0.0000877505,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007750487,"about_ca_topic_score_gemma":0.001468497,"domain_scores_codex":[0.9998814,0.00001098118,0.00001129768,0.00002614248,0.00003829851,0.00003184771],"domain_scores_gemma":[0.9999251,0.0000235568,0.00001508891,0.000005796099,0.00001914583,0.00001119106],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002623236,0.000006205884,0.00005000343,0.00001495977,0.000001734774,0.00001724302,0.000009938011,0.00002070094,0.9993618,0.00001453452,0.000006659441,0.0004699706],"study_design_scores_gemma":[0.000002840879,0.00004011116,0.0005288635,9.801968e-7,0.0000046534,0.00001681135,0.00000685684,0.0003306083,0.9989341,0.000003816901,0.0001294044,9.6653e-7],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9968675,0.0003231976,0.001851534,0.00002201501,0.00001411697,0.00001155008,0.00006226029,0.00005933607,0.0007885182],"genre_scores_gemma":[0.9953724,0.0004007121,0.002817338,0.00002830808,0.000005159121,0.00002633477,0.0001241625,0.00001967413,0.001206043],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007750487,"threshold_uncertainty_score":0.001998961,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01845881739511991,"score_gpt":0.2941439115339234,"score_spread":0.2756850941388035,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}