{"id":"W4404104994","doi":"10.1021/acs.chemrev.4c00373","title":"Dipolar Recoupling in Rotating Solids","year":2024,"lang":"en","type":"review","venue":"Chemical Reviews","topic":"Advanced NMR Techniques and Applications","field":"Chemistry","cited_by":25,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph","funders":"National Institute on Aging; National Institute of General Medical Sciences; Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Dipole; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002848991,0.0005204619,0.002091673,0.00006929183,0.00003100781,0.00004281053,0.0005292037,0.0004662811,0.0002896413],"category_scores_gemma":[0.0003339564,0.0003925349,0.0007696851,0.0004840805,0.00004255844,0.000044625,0.0002273226,0.001429188,0.0005955789],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002340977,"about_ca_system_score_gemma":0.00006580371,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000002006539,"about_ca_topic_score_gemma":4.87549e-7,"domain_scores_codex":[0.9973859,0.00001327007,0.001384436,0.0007241025,0.000121066,0.0003711855],"domain_scores_gemma":[0.9986546,0.0001489735,0.0003622207,0.0007099058,0.00001512765,0.0001091596],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[1.726336e-7,0.0000168741,1.039011e-7,0.05105102,0.000009304074,0.00000475499,0.000005626233,4.311644e-8,0.0002548208,0.0001305332,0.001534702,0.946992],"study_design_scores_gemma":[0.0000207439,0.000001129029,6.421588e-10,0.08142325,0.0002977813,0.00001565281,0.000001072073,0.00002715299,0.0002083227,0.0007007415,0.9169481,0.0003560659],"study_design_candidate":"design_other","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[9.376993e-7,0.9937117,0.0001692188,0.00001319497,0.00001982521,0.0004988352,0.00003071145,0.0002098857,0.005345724],"genre_scores_gemma":[2.789521e-7,0.9887701,0.007648607,0.00002599225,0.0003780054,0.001965636,0.000226822,0.0001161901,0.0008684199],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.946636,"threshold_uncertainty_score":0.9998527,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.09177753714342224,"score_gpt":0.4205675216716258,"score_spread":0.3287899845282035,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}