{"id":"W4404672969","doi":"10.1021/acs.orglett.4c04200","title":"1,3-Dipolar Cycloaddition of SF<sub>5</sub>-Alkynes with Nonstabilized Diazo: Synthesis of Highly Substituted SF<sub>5</sub>-3<i>H</i>-Pyrazoles","year":2024,"lang":"en","type":"article","venue":"Organic Letters","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal; Centre in Green Chemistry and Catalysis","funders":"Fonds de recherche du Québec – Nature et technologies; Natural Sciences and Engineering Research Council of Canada; Université de Montréal; Canada Foundation for Innovation","keywords":"Chemistry; Diazo; Cycloaddition; Medicinal chemistry; 1,3-Dipolar cycloaddition; Cyclopentanes; Deuterium; Organic chemistry; Stereochemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009635614,0.0002577578,0.0001637441,0.00008942435,0.0001484865,0.0001172157,0.000230273,0.0002291619,0.00224949],"category_scores_gemma":[0.0001001635,0.0001010598,0.000188825,0.0001261846,0.0001506915,0.0001541733,0.0001347894,0.0003540491,0.0005100367],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002494453,"about_ca_system_score_gemma":0.0001994906,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007090928,"about_ca_topic_score_gemma":0.00197888,"domain_scores_codex":[0.9999264,0.000006441799,0.000003912436,0.00001283052,0.00001611924,0.0000343037],"domain_scores_gemma":[0.9999713,0.000005094692,0.000009466918,0.000003864344,0.000004467098,0.000005933632],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001065519,0.00002684116,0.0001804318,0.0001635564,0.00001261646,0.0003094605,0.0000779397,0.0004894272,0.9916084,0.0008258802,0.0003336051,0.005865232],"study_design_scores_gemma":[0.0000153912,0.0002949722,0.001350799,0.00000697782,0.000008530493,0.0003093907,0.00003388153,0.0005744465,0.991976,0.0001165214,0.005302924,0.0000102454],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9756532,0.001610683,0.009914499,0.0001326978,0.00007489686,0.0000903382,0.0004274928,0.0001152108,0.01198085],"genre_scores_gemma":[0.9942286,0.0008807913,0.003098816,0.00003515199,0.000006011589,0.00002249979,0.0001170683,0.00001474738,0.001596312],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00224949,"threshold_uncertainty_score":0.007525265,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02181896709694923,"score_gpt":0.2878258608975369,"score_spread":0.2660068938005877,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}