{"id":"W4405015583","doi":"10.1021/jacs.4c11054","title":"Intramolecular Csp<sup>3</sup>-H Activation at a Platinum(IV) Center Resulting from O<sub>2</sub> Activation: The Role of a Proton-Responsive Ligand and Trans Influence","year":2024,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Brandon University; University of Calgary; University of British Columbia","funders":"University of British Columbia Graduate School; Natural Sciences and Engineering Research Council of Canada; Canada First Research Excellence Fund; Canada Foundation for Innovation","keywords":"Chemistry; Intramolecular force; Platinum; Ligand (biochemistry); Center (category theory); Proton; Stereochemistry; Medicinal chemistry; Crystallography; Catalysis; Organic chemistry; Nuclear physics; Receptor","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006032084,0.000210501,0.00009508675,0.00003042272,0.00009315614,0.0001519295,0.0002249991,0.0001824403,0.001594015],"category_scores_gemma":[0.0001017495,0.0000778792,0.00009192734,0.00004551027,0.0002167068,0.0001800711,0.0002636917,0.0002451104,0.0002305872],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001749444,"about_ca_system_score_gemma":0.0001197309,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004048298,"about_ca_topic_score_gemma":0.000726346,"domain_scores_codex":[0.9999577,0.000003492945,0.000001557989,0.000009896954,0.000009121642,0.00001815146],"domain_scores_gemma":[0.999976,0.00000730464,0.000007293043,0.000003014155,0.00000190618,0.000004406104],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003491082,0.00002954583,0.0006950339,0.0001063066,0.00001137216,0.0003142107,0.00008863,0.0004656763,0.9894251,0.001273871,0.0003095265,0.006931699],"study_design_scores_gemma":[0.00001131106,0.0001178362,0.0009537754,0.000002445624,0.000004497118,0.0001201002,0.00003308243,0.001463367,0.996129,0.0001481312,0.001012696,0.000003624298],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9924113,0.0002024026,0.002728139,0.00007010854,0.00001967919,0.00001102544,0.00005912291,0.00004860689,0.004449719],"genre_scores_gemma":[0.9991573,0.0000601783,0.0003226509,0.00001217803,0.00000238062,0.000002223691,0.00002606015,0.000005983753,0.0004110725],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001594015,"threshold_uncertainty_score":0.00533247,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007923132149843628,"score_gpt":0.2526294566898526,"score_spread":0.244706324540009,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}