{"id":"W4405436694","doi":"10.1016/j.jpba.2024.116643","title":"First separation of commendamide enantiomers","year":2024,"lang":"en","type":"article","venue":"Journal of Pharmaceutical and Biomedical Analysis","topic":"Analytical Chemistry and Chromatography","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"Canada First Research Excellence Fund; Shota Rustaveli National Science Foundation; Consiglio Nazionale delle Ricerche","keywords":"Chemistry; Enantiomer; Chromatography; Separation (statistics); Stereochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002718336,0.001128489,0.0004156188,0.0005778111,0.0003764417,0.0005406314,0.0005705408,0.0007373274,0.002294852],"category_scores_gemma":[0.0007679514,0.0002669901,0.0003973748,0.0003959387,0.0004667842,0.000552366,0.0007272464,0.0008779667,0.001523967],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004297624,"about_ca_system_score_gemma":0.0005982022,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001326578,"about_ca_topic_score_gemma":0.001476264,"domain_scores_codex":[0.9995585,0.00006196947,0.00002203142,0.0001181393,0.0001544922,0.00008474546],"domain_scores_gemma":[0.999709,0.00007170391,0.00005093547,0.00003624084,0.00007717169,0.00005501522],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002146685,0.00003056126,0.000320416,0.00009669061,0.00002548764,0.000377581,0.00007174398,0.00009454323,0.9851685,0.0006958617,0.0004078334,0.01249614],"study_design_scores_gemma":[0.000008942683,0.00007638246,0.0006575115,0.000009636785,0.00001189552,0.0003888924,0.0000278633,0.0008373187,0.9925861,0.00008152697,0.005300647,0.00001321275],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.77028,0.01337614,0.173161,0.0008202444,0.0006103846,0.0005623492,0.002275662,0.002100769,0.03681349],"genre_scores_gemma":[0.8972356,0.006295973,0.08351844,0.0004835587,0.0001013036,0.0001340508,0.001604137,0.0003172478,0.01030975],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002294852,"threshold_uncertainty_score":0.007677019,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01593686748364752,"score_gpt":0.3353154673371467,"score_spread":0.3193785998534991,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}