{"id":"W4405654634","doi":"10.26434/chemrxiv-2024-nkqt1","title":"Terpene-derived polyester-block-polycarbonates using metal-free catalysis","year":2024,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Carbon dioxide utilization in catalysis","field":"Chemical Engineering","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland","funders":"Newfoundland and Labrador; Memorial University of Newfoundland; Mitacs; Canada Foundation for Innovation; Natural Sciences and Engineering Research Council of Canada; Fulbright Canada","keywords":"Polyester; Polymer chemistry; Cyclohexene oxide; Propylene oxide; Polymer; Organic chemistry; Chemistry; Polymerization; Maleic anhydride; Copolymer; Materials science; Ethylene oxide","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002787285,0.001005168,0.00127627,0.0007242472,0.00007347967,0.0003850527,0.001619576,0.0008854902,0.0003909252],"category_scores_gemma":[0.000509336,0.001081494,0.001181878,0.0009877792,0.0001835722,0.0001391234,0.00553876,0.001505669,0.0001945984],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006185611,"about_ca_system_score_gemma":0.0002116426,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005006602,"about_ca_topic_score_gemma":0.0000301201,"domain_scores_codex":[0.9957497,0.00004294782,0.001101502,0.001603724,0.0007711374,0.0007310598],"domain_scores_gemma":[0.9958828,0.0001842401,0.0003497376,0.0030722,0.0001863003,0.0003247258],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001765992,0.00008595338,0.0001434273,0.001320897,0.002054059,0.0001071616,0.0004548204,0.01763401,0.9771513,0.0002605925,0.0004639054,0.0003062451],"study_design_scores_gemma":[0.0003479436,0.000005496017,0.0000265,0.0005226398,0.002138915,0.00004106999,0.00009756484,0.1464481,0.8463784,0.002325341,0.0004565347,0.001211544],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9828075,0.00708595,0.001182406,0.0004514349,0.001876772,0.0004310844,0.00008266648,0.001545304,0.004536949],"genre_scores_gemma":[0.9943483,0.00007552492,0.002235509,0.00009635767,0.00073804,0.0001509519,0.0004506766,0.0003679063,0.001536733],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1307729,"threshold_uncertainty_score":0.9991635,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02221514737266852,"score_gpt":0.259606747198262,"score_spread":0.2373915998255935,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}