{"id":"W4405707800","doi":"10.1002/ange.202422275","title":"Extended Tetrathiafulvalene Multi‐Redox Systems Incorporating 4,5‐Dihydroazuleno[2,1,8‐<i>ija</i>]azulene Cores","year":2024,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Organic and Molecular Conductors Research","field":"Materials Science","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"Novo Nordisk Fonden","keywords":"Chemistry; Tetrathiafulvalene; Dication; Azulene; Photochemistry; Thiophene; Chromophore; Annulene; Cyclobutadiene; Singlet state; Aromaticity; Redox; Molecule; Computational chemistry; Organic chemistry; Excited state","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007084604,0.0002177931,0.0002257517,0.0001177952,0.0001349867,0.000296129,0.0003191662,0.000221955,0.001071526],"category_scores_gemma":[0.00009614467,0.00009662693,0.0001081938,0.0001183928,0.0001321259,0.0003178437,0.0001900509,0.0002665721,0.0001904827],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003609028,"about_ca_system_score_gemma":0.0001105055,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005209786,"about_ca_topic_score_gemma":0.0007103779,"domain_scores_codex":[0.9999622,0.000005549099,0.000002802631,0.00001120004,0.000006965302,0.00001128707],"domain_scores_gemma":[0.9999537,0.000006042091,0.00001218057,0.000006160767,0.000006533793,0.00001528045],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000131912,0.00004289107,0.0001032318,0.00005022696,0.0000110265,0.00004846846,0.00003035689,0.001148507,0.9959491,0.0006068561,0.00003944548,0.001837952],"study_design_scores_gemma":[0.00003993856,0.0005795343,0.0008204539,0.000006024378,0.00001674623,0.00005376469,0.00002316386,0.0090473,0.9871016,0.0001383614,0.002155625,0.00001771633],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9976071,0.0001737726,0.001515504,0.00001301547,0.000007290867,0.00001050009,0.00004354582,0.00003843173,0.0005907988],"genre_scores_gemma":[0.9974836,0.0001378641,0.001603339,0.00000681619,0.000001754927,0.00001775046,0.0000728463,0.000007284264,0.0006688591],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001071526,"threshold_uncertainty_score":0.003584564,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03026036925826849,"score_gpt":0.2867271484934402,"score_spread":0.2564667792351717,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}