{"id":"W4405720237","doi":"10.1021/jacs.4c11776","title":"Fluoroform (CHF<sub>3</sub>) Production from CF<sub>3</sub>CHO Photolysis and Implications for the Decomposition of Hydrofluoroolefins and Hydrochlorofluoroolefins in the Atmosphere","year":2024,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Atmospheric Ozone and Climate","field":"Earth and Planetary Sciences","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Australian Research Council; University of New South Wales","keywords":"Chemistry; Atmosphere (unit); Photodissociation; Decomposition; Photochemistry; Organic chemistry; Meteorology","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002307097,0.0002590061,0.00009496967,0.0001287217,0.0002530591,0.0001908587,0.0001559565,0.0003326021,0.001423057],"category_scores_gemma":[0.0002557152,0.00009485237,0.000143864,0.0001021433,0.0004817973,0.0002879232,0.0002345272,0.0002001766,0.0001469023],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004304213,"about_ca_system_score_gemma":0.0001657768,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002036849,"about_ca_topic_score_gemma":0.001920875,"domain_scores_codex":[0.9999193,0.000009754317,0.000002375182,0.00001686725,0.00002501894,0.00002662595],"domain_scores_gemma":[0.9999213,0.00002693852,0.00002944378,0.000005555406,0.00001150426,0.000005152896],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009302694,0.000007061472,0.001036116,0.00004019948,0.000002448319,0.00006144274,0.00002483797,0.0001273124,0.9967229,0.00018463,0.000053787,0.001646152],"study_design_scores_gemma":[0.0000107557,0.0001558357,0.01184747,0.000006834592,0.000005944382,0.0001241599,0.00003929051,0.0004228338,0.9865002,0.0001017056,0.0007788879,0.000006019232],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9942621,0.0005399121,0.002476807,0.00009420334,0.00001101481,0.00002255206,0.0002967593,0.00003058107,0.002266115],"genre_scores_gemma":[0.9976591,0.0003701593,0.001305811,0.000031226,0.000003943992,0.000009166281,0.0001283955,0.000005636915,0.0004866991],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002036849,"threshold_uncertainty_score":0.004760623,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008279957733128488,"score_gpt":0.2317682095400776,"score_spread":0.2234882518069491,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}