{"id":"W4405774658","doi":"10.1016/j.jfluchem.2024.110386","title":"Exploration towards the bromopentafluorosulfanylation reaction of terminal alkynes","year":2024,"lang":"en","type":"article","venue":"Journal of Fluorine Chemistry","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval; PROTEO","funders":"Natural Sciences and Engineering Research Council of Canada; Université de Rouen; Normandie Université; Agence Nationale de la Recherche; Indian National Science Academy; Centre National de la Recherche Scientifique; Fonds de recherche du Québec – Nature et technologies; Région Normandie; Université Laval","keywords":"Chemistry; Terminal (telecommunication); Combinatorial chemistry; Stereochemistry; Medicinal chemistry; Computer network","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002939759,0.0003607671,0.0001884719,0.0001459178,0.0001337213,0.0001806395,0.0002554052,0.0003995887,0.0008811572],"category_scores_gemma":[0.0002238763,0.000124122,0.0002707261,0.0001340137,0.0001890607,0.0002831478,0.000289253,0.0004460761,0.0003611176],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001842387,"about_ca_system_score_gemma":0.0002966012,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004915965,"about_ca_topic_score_gemma":0.0007753707,"domain_scores_codex":[0.9998584,0.00002865065,0.000009609505,0.00002589227,0.00003415509,0.00004321492],"domain_scores_gemma":[0.9999284,0.0000133051,0.0000157113,0.00001071,0.00001988666,0.00001203535],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007782589,0.00005331646,0.0002414826,0.0002796021,0.00001915191,0.0004180595,0.0001421127,0.0003933629,0.9895903,0.001121724,0.0001577724,0.007505215],"study_design_scores_gemma":[0.00002794767,0.0006487891,0.0008680111,0.00001829465,0.0000256284,0.0008590705,0.00004020237,0.0007019457,0.9869551,0.0003182413,0.009519755,0.00001695718],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.954804,0.004543845,0.03133662,0.0003225249,0.0000632083,0.0001675926,0.0002316867,0.00009341528,0.008437146],"genre_scores_gemma":[0.9772415,0.005186636,0.01370163,0.00007580918,0.00001641383,0.00004424475,0.0001625789,0.00002255546,0.003548547],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008811572,"threshold_uncertainty_score":0.002947807,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.1098334008316161,"score_gpt":0.4142980242720716,"score_spread":0.3044646234404556,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}