{"id":"W4405800768","doi":"10.1039/d4cy01358a","title":"Kinetics, quantum yield and mechanism of the decatungstate-catalyzed photooxidation of C–H hydrogen donors: role of the persistent radical effect","year":2024,"lang":"en","type":"article","venue":"Catalysis Science & Technology","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Canada Foundation for Innovation","keywords":"Photochemistry; Catalysis; Quantum yield; Chemistry; Kinetics; Yield (engineering); Mechanism (biology); Hydrogen; Materials science; Organic chemistry; Fluorescence; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004830426,0.0002485062,0.0002053281,0.0001206144,0.0001266657,0.0001900096,0.0003521903,0.0003089021,0.001531745],"category_scores_gemma":[0.0004818665,0.0001296643,0.0001730232,0.0001013146,0.0002634086,0.0004443937,0.0001280195,0.0005671646,0.000216017],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004339193,"about_ca_system_score_gemma":0.0002079311,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008249127,"about_ca_topic_score_gemma":0.000560021,"domain_scores_codex":[0.9999344,0.000009405385,0.000003268798,0.00002105769,0.00001371516,0.00001818334],"domain_scores_gemma":[0.999651,0.0002057631,0.00005151083,0.00003202586,0.00003677752,0.00002300252],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003357575,0.00004890685,0.001635881,0.0001027415,0.00001787191,0.00007130593,0.0001164941,0.001113439,0.9890639,0.0009948527,0.0001156387,0.006383181],"study_design_scores_gemma":[0.000006975214,0.0001588399,0.0016733,0.000001888903,0.00001044501,0.00004932989,0.00002209445,0.004082534,0.99349,0.0001749287,0.0003214198,0.000008320887],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9924004,0.000831521,0.005719535,0.00007701905,0.00001455683,0.000019793,0.0001793888,0.0000477371,0.000709992],"genre_scores_gemma":[0.9986695,0.0002108209,0.000618352,0.00000497956,0.000003434522,0.00000689041,0.00005660672,0.000006072282,0.0004232723],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001531745,"threshold_uncertainty_score":0.005124211,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005966401359528318,"score_gpt":0.2216205718002323,"score_spread":0.215654170440704,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}