{"id":"W4406235058","doi":"10.1021/acs.inorgchem.4c03689","title":"Rationalizing Photophysics of Co(III) Complexes with Pendant Pyrene Moieties","year":2025,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada; University of British Columbia","keywords":"Chemistry; Photochemistry; Chromophore; Excited state; Singlet state; Ultrafast laser spectroscopy; Triplet state; Moiety; Pyrene; Pyridine; Molecule; Stereochemistry; Spectroscopy; Organic chemistry; Atomic physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009283699,0.0003197445,0.0002271072,0.0001172136,0.0002316824,0.0005359925,0.0003556951,0.0003638831,0.000963861],"category_scores_gemma":[0.0002469506,0.0002679818,0.0002176075,0.0001080562,0.0002113569,0.0002582798,0.0001504034,0.0003971569,0.0002223576],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001168154,"about_ca_system_score_gemma":0.0003869219,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002379244,"about_ca_topic_score_gemma":0.003432505,"domain_scores_codex":[0.9999534,0.000004507484,0.00000213007,0.00001127419,0.00001309201,0.00001556762],"domain_scores_gemma":[0.999944,0.00002152978,0.00001359102,0.000005412965,0.000007696236,0.00000775364],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000208211,0.0002235956,0.001700255,0.0002191246,0.00002564487,0.0003255063,0.0001072726,0.1168757,0.8695884,0.004512274,0.000325702,0.005888262],"study_design_scores_gemma":[0.00006213038,0.0002733418,0.001489579,0.000009878535,0.0000247292,0.00008142357,0.00009671317,0.3757645,0.6198966,0.0005222716,0.001757193,0.0000216132],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9930936,0.0001435515,0.004453262,0.00009052754,0.000009151174,0.00004141922,0.0001031187,0.00007837726,0.001986934],"genre_scores_gemma":[0.9965771,0.0001480582,0.002671789,0.0000202588,0.000001566414,0.00004058273,0.00009655755,0.00001698008,0.000427187],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002379244,"threshold_uncertainty_score":0.008475542,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00948306367544318,"score_gpt":0.2439166662009053,"score_spread":0.2344336025254621,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}