{"id":"W4406432675","doi":"10.26434/chemrxiv-2025-rpknn","title":"Non-covalent Interactions Promoted Kinetics in Perylene Diimide-based Aqueous Zn-ion Batteries: an operando ATR-IR Study","year":2025,"lang":"en","type":"preprint","venue":"ChemRxiv","topic":"Advanced battery technologies research","field":"Engineering","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Perylene; Diimide; Kinetics; Aqueous solution; Covalent bond; Ion; Chemistry; Photochemistry; Materials science; Organic chemistry; Molecule; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002352491,0.0006464465,0.0007551118,0.0008452589,0.00007636418,0.0001449572,0.001144497,0.000432827,0.0001468632],"category_scores_gemma":[0.0001777694,0.0006875892,0.0001410746,0.000602965,0.0001167819,0.0001693546,0.0009833189,0.002212376,0.00002939554],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0009517132,"about_ca_system_score_gemma":0.0001191158,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008857965,"about_ca_topic_score_gemma":0.0003156517,"domain_scores_codex":[0.997218,0.00007861116,0.0007373869,0.0009308066,0.0003786129,0.0006566516],"domain_scores_gemma":[0.9977032,0.0001420099,0.00008834612,0.001788989,0.0001655987,0.0001118851],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"simulation_or_modeling","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004822635,0.004812418,0.0204557,0.004656046,0.0006063745,0.000852624,0.003416877,0.7459946,0.1718884,0.000005286883,0.001415951,0.04541347],"study_design_scores_gemma":[0.006875841,0.001145663,0.02878326,0.003033509,0.0001940576,0.00002613354,0.00261339,0.2941107,0.6560761,0.0004419852,0.003572125,0.003127211],"study_design_candidate":"simulation_or_modeling","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9827078,0.0001671228,0.01161042,0.0003594852,0.0008645769,0.002434519,0.00003356527,0.001204947,0.0006175692],"genre_scores_gemma":[0.9951884,0.0001320695,0.002484666,0.00004074593,0.0001021063,0.001378358,0.0001763247,0.0001112758,0.000386013],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4841877,"threshold_uncertainty_score":0.9995576,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02842606967888294,"score_gpt":0.3142711044525232,"score_spread":0.2858450347736402,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}