{"id":"W4406760924","doi":"10.1002/anie.202500022","title":"Forward‐ and Retro‐Vapofluorochromism of Sponge‐Like Macrocycle Crystals","year":2025,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Luminescence and Fluorescent Materials","field":"Materials Science","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"Ministry of Education and Child Care","funders":"National Key Research and Development Program of China; Basic Research Program of Jiangsu Province; Government of Jiangsu Province; Natural Science Foundation of Jiangsu Province; National Natural Science Foundation of China","keywords":"Amine gas treating; Crystal (programming language); Molecule; Luminescence; Solid-state; Materials science; Chemistry; Crystallography; Photochemistry; Nanotechnology; Organic chemistry; Optoelectronics; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002458404,0.0001229252,0.0001931197,0.0001093722,0.00005773594,0.00006803268,0.0002101959,0.000089887,0.0009196173],"category_scores_gemma":[0.0001144245,0.000115397,0.00005102992,0.00007105164,0.0001303577,0.000330964,0.0001093302,0.00004997348,0.00002590885],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006269132,"about_ca_system_score_gemma":0.00003716665,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006872995,"about_ca_topic_score_gemma":0.000007342901,"domain_scores_codex":[0.9989705,0.0000179634,0.0003266068,0.000258003,0.0002698623,0.0001570381],"domain_scores_gemma":[0.99941,0.00005632856,0.0001451306,0.0001520733,0.0001933441,0.000043086],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000981683,0.00004807796,0.0004718808,0.00007126439,0.00001737433,0.000003647101,0.00009323561,7.308716e-7,0.9862869,0.0009712207,0.01176231,0.0001752232],"study_design_scores_gemma":[0.0005343458,0.00002323939,0.002294302,0.0001663401,0.00002201344,0.00000764584,0.00005323634,0.00001370346,0.9882388,0.002791801,0.005752383,0.0001022645],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9846714,0.0001801253,0.001557999,0.0009194216,0.002816642,0.0001662541,0.0002164239,0.00006342378,0.009408356],"genre_scores_gemma":[0.9974575,0.0001343478,0.0004935502,0.0003005396,0.000440474,0.00002299578,0.0001415503,0.00000844537,0.001000593],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01278615,"threshold_uncertainty_score":0.9999937,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007706061401342493,"score_gpt":0.2539239434048887,"score_spread":0.2462178820035462,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}